Directed Synthesis of {Mn18Cu6} Heterometallic Complexes

Victoria A. Milway; Floriana Tuna; Andrew R. Farrell; Laura E. Sharp; Simon Parsons; Mark Murrie

doi:10.1002/anie.201208781

Directed Synthesis of {Mn18Cu6} Heterometallic Complexes

Victoria A. Milway, Floriana Tuna, Andrew R. Farrell, Laura E. Sharp, Simon Parsons, Mark Murrie

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

A two-step method for the directed synthesis of high-nuclearity MnIII-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core.

Original language	English
Pages (from-to)	1949-1952
Journal	Angewandte Chemie International Edition
Volume	52
Issue number	7
DOIs	https://doi.org/10.1002/anie.201208781
Publication status	Published - 11 Feb 2013

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title = "Directed Synthesis of {Mn18Cu6} Heterometallic Complexes",

abstract = "A two-step method for the directed synthesis of high-nuclearity MnIII-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core.",

author = "Milway, {Victoria A.} and Floriana Tuna and Farrell, {Andrew R.} and Sharp, {Laura E.} and Simon Parsons and Mark Murrie",

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AU - Milway, Victoria A.

AU - Tuna, Floriana

AU - Farrell, Andrew R.

AU - Sharp, Laura E.

AU - Parsons, Simon

AU - Murrie, Mark

PY - 2013/2/11

Y1 - 2013/2/11

N2 - A two-step method for the directed synthesis of high-nuclearity MnIII-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core.

AB - A two-step method for the directed synthesis of high-nuclearity MnIII-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core.

U2 - 10.1002/anie.201208781

DO - 10.1002/anie.201208781

M3 - Article

SN - 1433-7851

VL - 52

SP - 1949

EP - 1952

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 7

ER -

Directed Synthesis of {Mn18Cu6} Heterometallic Complexes

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