Dissociative adsorption of pyrrole on Si(111)-(7×7)

Ze Liang Yuan, Xian Feng Chen, Zhong Hai Wang, Kian Soon Yong, Yong Cao, Guo Qin Xu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The dissociative chemisorption of pyrrole molecules on Si(111)-(7×7) was investigated using HREELS, TDS, STM, and theoretical calculation. The pyrrolyl radical and H atom formed via the N-H bond cleavage were found to be bonded to the adjacent adatom and rest atom, respectively. Analyses of the spatial distribution of reacted adatoms showed that the adsorption is highly site selective.

Original languageEnglish
Pages (from-to)10389-10395
Number of pages7
JournalJournal of Chemical Physics
Volume119
Issue number19
DOIs
Publication statusPublished - 15 Nov 2003

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