Projects per year
Abstract
Here we investigate the modulation of solvent isotope effects by the entry of DNA molecules into individual α-haemolysin nanopores. Solvent isotope effects in D2O versus H2O were enhanced (kH/kD ≈ 1.6) compared to the bulk (kH/kD ≈ 1.2), except when the pore was most blocked (kH/kD ≤ 1.1).
Original language | English |
---|---|
Pages (from-to) | 12243-12246 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 61 |
Early online date | 23 Jun 2015 |
DOIs | |
Publication status | Published - 23 Jun 2015 |
Keywords / Materials (for Non-textual outputs)
- nanopores
- DNA
- isotope effects
- solvent effects
Fingerprint
Dive into the research topics of 'DNA Modulates Solvent Isotope Effects in a Nanopore'. Together they form a unique fingerprint.Projects
- 2 Finished
-
TransPoreT: Transmembrane Molecular Machines
Cockroft, S. (Principal Investigator)
1/09/13 → 31/08/18
Project: Research
-
Organic supramolecular chemistry: A Research programme of synthetic molecular motors and machines
Leigh, D. (Principal Investigator)
1/01/10 → 30/12/14
Project: Research
Datasets
-
DNA modulates solvent isotope effects in a nanopore
Watson, M. (Creator) & Cockroft, S. (Creator), Edinburgh DataShare, 1 Jul 2015
DOI: 10.7488/ds/277, http://dx.doi.org/10.1039/C5CC01563D
Dataset