Dodecanuclear [MnIII6LnIII6] species: synthesis, structures and characterization of magnetic relaxation phenomena

Thomais G. Tziotzi, Demetrios I. Tzimopoulos, Tadeusz Lis, Ross Inglis, Constantinos J. Milios

Research output: Contribution to journalArticlepeer-review

Abstract

The use of H3L (= 2-(β-naphthalideneamino)-2-hydroxymethyl-1-propanol) in mixed-metal manganese–lanthanide carboxylate cluster chemistry has led to the isolation of two new dodecametallic heteronuclear isostructural [MnIII6LnIII6] complexes (Ln = Gd, Dy), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals suggesting possible single molecule magnetism behaviour.
Original languageEnglish
Pages (from-to)11696-11699
Number of pages4
JournalDalton Transactions
Volume44
Issue number26
DOIs
Publication statusPublished - 2 Jun 2015

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