Double-stranded, [4+4] helicates of Fe(II) and Mn(II) supported by an extended dipyrrolide ligand

S D Reid, A J Blake, W Kockenberger, W A Claire, J B Love

Research output: Contribution to journalArticlepeer-review

Abstract

Transamination reactions between Mn and Fe amides and the diiminodipyrromethane H2L result in the spontaneous formation of volatile, double-stranded helicates that exhibit distinct major and minor grooves.

Original languageEnglish
Pages (from-to)4387-4388
Number of pages2
JournalDalton Transactions
Issue number23
DOIs
Publication statusPublished - 2003

Keywords

  • IRON(II) COMPLEX
  • DOUBLE-HELIX
  • GROOVE

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