Electrochemical phase-transfer catalysis in microemulsions: Carbene formation

C J Campbell, J F Rusling

Research output: Contribution to journalLetterpeer-review

Abstract

Dicholocarbene can be generated at a carbon cathode from dichlorodibromomethane in microemulsions. The carbene then reacts with the organic constituent of the microemulsion to generate 7,7-dichlorobicycloheptane. A variety of reaction conditions were investigated, and the best conditions give a current efficiency of 80%.

Original languageEnglish
Pages (from-to)7416-7417
Number of pages2
JournalLangmuir
Volume15
Issue number22
Publication statusPublished - 26 Oct 1999

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