Enantiomorphic symmetry breaking in crystallization of molten sodium chlorate

Martin R. Ward, Gary W. Copeland, Andrew J. Alexander

Research output: Contribution to journalArticlepeer-review

Abstract

Enantiomorphic symmetry breaking of stirred samples of molten sodium chlorate is demonstrated, revealing the unexpected involvement of an achiral solid phase. The results should stimulate future computational models of nucleation, including symmetry breaking, and have implications for mechanisms that invoke enantiomorphism in natural minerals to explain biohomochirality.

Original languageEnglish
Pages (from-to)7634-7636
Number of pages3
JournalChemical Communications
Volume46
Issue number40
DOIs
Publication statusPublished - 2010

Keywords

  • ENANTIOSELECTIVE SYNTHESIS
  • ASYMMETRIC AUTOCATALYSIS
  • 1,1'-BINAPHTHYL MELT
  • AMPLIFICATION
  • POLYMORPHISM
  • CRYSTALS
  • QUARTZ
  • ACID

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