Abstract
Put a nickel in it: Azaarylacetates and acetamides, which have been neglected as substrates in catalytic asymmetric synthesis, undergo highly enantioselective Michael additions to nitroalkenes in the presence of a chiral nickel(II)-bis(diamine) complex (see scheme; Bn=benzyl, MS=molecular sieves). This process is tolerant of a wide variety of azaarenes in the pronucleophile.
| Original language | English |
|---|---|
| Pages (from-to) | 11214-11218 |
| Number of pages | 5 |
| Journal | Chemistry - A European Journal |
| Volume | 18 |
| Issue number | 36 |
| DOIs | |
| Publication status | Published - 3 Sept 2012 |
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