Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes

Graham Pattison, Guillaume Piraux, Hon Wai Lam

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

In the presence of a rhodium complex containing a newly developed chiral diene ligand, alkenes activated by a range of pi-deficient or pi-excessive heteroarenes engage in highly enantioselective conjugate additions with various arylboronic acids.

Original languageEnglish
Pages (from-to)14373-14375
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number41
DOIs
Publication statusPublished - 20 Oct 2010

Keywords / Materials (for Non-textual outputs)

  • ASYMMETRIC CONJUGATE ADDITION
  • CHIRAL DIENE LIGANDS
  • RH/M-TPPTC CATALYST
  • BORONIC ACIDS
  • TRISUBSTITUTED ALKENES
  • COUPLING REACTIONS
  • BOND FORMATION
  • 1,4-ADDITION
  • AROMATICITY
  • RING

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