Abstract
Chiral allylrhodium nucleophiles: The highly diastereo- and enantioselective title reaction of a range of cyclic imines with various potassium allyltrifluoroborates most likely proceeds via allylrhodium(I) intermediates, and represents the first rhodium-catalyzed enantioselective nucleophilic allylation of π electrophiles with allylboron compounds.
Original language | English |
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Pages (from-to) | 8309-8313 |
Number of pages | 5 |
Journal | Angewandte Chemie International Edition |
Volume | 51 |
Issue number | 33 |
DOIs | |
Publication status | Published - 2012 |