Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle

James W. Leeland, Fraser J. White, Jason B. Love

Research output: Contribution to journalArticlepeer-review

Abstract

Hydrolysis of a Pacman-shaped binuclear magnesium complex of a polypyrrolic Schiff base macrocycle results in the formation of a new magnesium hydroxide cubane that is encapsulated by the macrocyclic framework through both coordinative and hydrogen-bonding interactions.

Original languageEnglish
Pages (from-to)7320-7323
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number19
DOIs
Publication statusPublished - 18 May 2011

Keywords

  • HYDROGEN-BONDS
  • INTERMOLECULAR FORCES
  • EXPANDED PORPHYRIN
  • DIELS-ALDER
  • COMPLEXES
  • CAPSULES
  • HOST
  • CATALYSIS
  • STABILIZATION
  • ACTIVATION

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