Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components

Mohammed Hashem; C. Grazia Bezzu; Benson M. Kariuki; Neil B. McKeown

doi:10.1039/c1py00288k

Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components

Mohammed Hashem, C. Grazia Bezzu, Benson M. Kariuki, Neil B. McKeown^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

By combining both triptycene and multifunctional phthalocyanine components within a polymer of intrinsic microporosity (PIM), a polymer network of apparent BET surface of 806 m(2) g(-1) was obtained that appears to possess a highly rigid structure as determined from the shape of its nitrogen adsorption isotherm, which is similar in appearance to that of a crystalline microporous material such as a zeolite.

Original language	English
Pages (from-to)	2190-2192
Number of pages	3
Journal	Polymer Chemistry
Volume	2
Issue number	10
DOIs	https://doi.org/10.1039/c1py00288k
Publication status	Published - 2011

Keywords / Materials (for Non-textual outputs)

HIGH-SURFACE-AREA
ORGANIC MATERIALS
ADSORPTION
FRAMEWORKS
CATALYSIS
CHEMISTRY
MONOMERS
PIMS

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title = "Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components",

abstract = "By combining both triptycene and multifunctional phthalocyanine components within a polymer of intrinsic microporosity (PIM), a polymer network of apparent BET surface of 806 m(2) g(-1) was obtained that appears to possess a highly rigid structure as determined from the shape of its nitrogen adsorption isotherm, which is similar in appearance to that of a crystalline microporous material such as a zeolite.",

keywords = "HIGH-SURFACE-AREA, ORGANIC MATERIALS, ADSORPTION, FRAMEWORKS, CATALYSIS, CHEMISTRY, MONOMERS, PIMS",

author = "Mohammed Hashem and Bezzu, {C. Grazia} and Kariuki, {Benson M.} and McKeown, {Neil B.}",

year = "2011",

doi = "10.1039/c1py00288k",

language = "English",

volume = "2",

pages = "2190--2192",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "10",

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T1 - Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components

AU - Hashem, Mohammed

AU - Bezzu, C. Grazia

AU - Kariuki, Benson M.

AU - McKeown, Neil B.

PY - 2011

Y1 - 2011

N2 - By combining both triptycene and multifunctional phthalocyanine components within a polymer of intrinsic microporosity (PIM), a polymer network of apparent BET surface of 806 m(2) g(-1) was obtained that appears to possess a highly rigid structure as determined from the shape of its nitrogen adsorption isotherm, which is similar in appearance to that of a crystalline microporous material such as a zeolite.

AB - By combining both triptycene and multifunctional phthalocyanine components within a polymer of intrinsic microporosity (PIM), a polymer network of apparent BET surface of 806 m(2) g(-1) was obtained that appears to possess a highly rigid structure as determined from the shape of its nitrogen adsorption isotherm, which is similar in appearance to that of a crystalline microporous material such as a zeolite.

KW - HIGH-SURFACE-AREA

KW - ORGANIC MATERIALS

KW - ADSORPTION

KW - FRAMEWORKS

KW - CATALYSIS

KW - CHEMISTRY

KW - MONOMERS

KW - PIMS

U2 - 10.1039/c1py00288k

DO - 10.1039/c1py00288k

M3 - Article

SN - 1759-9954

VL - 2

SP - 2190

EP - 2192

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 10

ER -

Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components

Abstract

Keywords / Materials (for Non-textual outputs)

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