Enhancing U-eff in oxime-bridged [Mn(6)(III)Ln(2)(III)] hexagonal prisms

Guillaume Rigaux, Ross Inglis, Susan Morrison, Alessandro Prescimone, Cyril Cadiou, Marco Evangelisti, Euan K. Brechin

Research output: Contribution to journalArticlepeer-review

Abstract

The first 3d-4f clusters built using derivatised salicylaldoximes (R-saoH(2)) describe unusual hexagonal prisms. Replacement of the paramagnetic Gd(III) ions with diamagnetic Ln(III) ions allows for a more thorough understanding of the magnetic properties, whilst replacement with Tb(III) doubles U-eff.

Original languageEnglish
Pages (from-to)4797-4799
Number of pages3
JournalDalton Transactions
Volume40
Issue number18
DOIs
Publication statusPublished - 2011

Keywords

  • SINGLE-MOLECULE MAGNETS
  • COMPLEXES
  • CRYSTAL
  • 3D

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