@article{94f43293e4604089b2a23ad1b8c9bcfa,
title = "Exploring the Redox Properties of Bench-Stable Uranyl(VI) Diamido–Dipyrrin Complexes",
abstract = "The uranyl complexes UO2(OAc)(L) and UO2Cl(L) of the redox-active, acyclic diamido–dipyrrin anion L– are reported and their redox properties explored. Because of the inert nature of the complexes toward hydrolysis and oxidation, synthesis of both the ligands and complexes was conducted under ambient conditions. Voltammetric, electron paramagnetic resonance spectroscopy, and density functional theory studies show that one-electron chemical reduction by the reagent CoCp2 leads to the formation of a dipyrrin radical for both complexes [Cp2Co][UO2(OAc)(L•)] and [Cp2Co][UO2Cl(L•)].",
author = "{Van Rees}, Karlotta and Hield, {Emma K.} and Ambre Carpentier and Laurent Maron and Stephen Sproules and Love, {Jason B.}",
note = "Funding Information: The authors thank the University of Edinburgh, the EPSRC (U.K.), and the EPSRC CRITICAT Centre for Doctoral Training (Ph.D. studentship to K.v.R.; Grant EP/L016419/1) for financial support. L.M. is a senior member of the Institut Universtaire de France. CalMip is acknowledged for a generous grant of computing time. Publisher Copyright: {\textcopyright} 2022 American Chemical Society",
year = "2022",
month = feb,
day = "7",
doi = "10.1021/acs.inorgchem.1c03744",
language = "English",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
}