Projects per year
Abstract
To supplement our study on thiocyanate-free ruthenium sensitizers (TFRS) for dye-sensitized solar cells (DSSCs), which belong to a class of Ru-based complexes coordinated by a single 4,4'-dicarboxylic acid-2,2'-bipyridine and two symmetrically arranged functionalized trans-azolate chelates, we carefully isolated and characterized the second and less-abundant stereoisomer, in which the two pyridyl azolate ancillaries are asymetrically cis-arranged to each other. Two distinctive ancillaries, namely: 5-[4-(5-hexyl-2-thienyl)-2-pyridinyl]-3-trifluoromethyl pyrazole and 5-(6-tert-butyl-1-isoquinolinyl)-3-trifluoromethyl pyrazole, were employed in this study, giving a total of four sensitizers, that is, thienyl substituted TFRS-2a and 2b, and isoquinolinyl substituted TFRS-52a and 52b, in which the suffix b indicates the cis-stereoisomers. To gain insight into their fundamental properties their photophysical, electrochemical, and spectroelectrochemical behavior was investigated by density functional theory. Upon comparison of the correspondingly fabricated DSSCs, the sensitizers TFRS-2a and 52a yielded significantly higher conversion efficiencies than their asymmetrical cis-counterparts, TFRS-2b and 52b. To rationalize the cell performances charge extraction/photovoltage decay and impedance spectroscopic measurements were carried out to compare the rates of interfacial electron recombination from the TiO conduction band to the electrolyte.
Original language | English |
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Pages (from-to) | 1207–1215 |
Journal | ChemPhysChem |
Volume | 15 |
Issue number | 6 |
DOIs | |
Publication status | Published - 1 Jan 2014 |
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Dive into the research topics of 'Geometrical Isomerism of Ru Dye-Sensitized Solar Cell Sensitizers and Effects on Photophysical Properties and Device Performances'. Together they form a unique fingerprint.Projects
- 3 Finished
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GLOBAL - Edinburgh Pacific Partnership of Excellence in New Energy Technologies
Bruce, T. (Principal Investigator) & Attfield, P. (Co-investigator)
1/04/12 → 31/03/13
Project: Research
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Advancing the efficiency and production potential of Excitionic Solar Cells. (APEX)
Robertson, N. (Principal Investigator)
1/10/10 → 22/04/14
Project: Research
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SUPERGEN Excitonic Solar Cell Consortium
Robertson, N. (Principal Investigator)
1/04/09 → 30/09/13
Project: Research