Halide redistribution in Pd-catalysed 1,6-diene cycloisomerisation

KL Bray, IJS Fairlamb, GC Lloyd-Jones*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

[(MeCN)(3)PdCl](+), generated in situ, reversibly disproportionates to give [(MeCN)(2)PdCl2] and [(MeCN)(4)Pd](2+). The neutral species is a reactive and highly regioselective catalyst for 1,6-diene cycloisomerisation.

Original languageEnglish
Pages (from-to)187-188
Number of pages2
JournalChemical Communications
Issue number2
Publication statusPublished - 2001

Keywords

  • C-BOND FORMATION
  • CYCLIZATION
  • CYCLOISOMERIZATIONS
  • ALPHA,OMEGA-DIENES
  • HETEROCYCLES

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