New CaCrO3-delta superstructure phases (delta = 0.33, 0.4, and 0.5) have been discovered through 'soft' low temperature reduction of the perovskite CaCrO3 made at 'hard' high pressure-temperature conditions. Their structures form a related series based on stacking of octahedral and tetrahedral chromium oxide layers.
|Number of pages||4|
|Journal||Journal of Materials Chemistry C Materials for optical and electronic devices|
|Early online date||9 Oct 2014|
|Publication status||Published - 28 Nov 2014|