Hetero- Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal- Organic Frameworks with High Surface Areas

Nianyong Zhu, Matthew J. Lennox, Gerard Tobin, Lisa Goodman, Tina Dueren, Wolfgang Schmitt*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a topological blueprint. The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented Cu-II acetate-based MOFs.

Original languageEnglish
Pages (from-to)3595-3599
Number of pages5
JournalChemistry - A European Journal
Volume20
Issue number13
DOIs
Publication statusPublished - 24 Mar 2014

Keywords / Materials (for Non-textual outputs)

  • coordination chemistry
  • copper
  • epitaxy
  • metal-organic frameworks
  • supramolecular chemistry
  • HYDROGEN STORAGE
  • BUILDING UNITS
  • GAS-STORAGE
  • LARGE PORES
  • SOLIDS
  • ROBUST
  • CATALYSIS
  • CLUSTERS
  • POLYMER
  • DESIGN

Fingerprint

Dive into the research topics of 'Hetero- Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal- Organic Frameworks with High Surface Areas'. Together they form a unique fingerprint.

Cite this