Hetero- Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal- Organic Frameworks with High Surface Areas

Nianyong Zhu; Matthew J. Lennox; Gerard Tobin; Lisa Goodman; Tina Dueren; Wolfgang Schmitt

doi:10.1002/chem.201304856

Hetero- Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal- Organic Frameworks with High Surface Areas

Nianyong Zhu, Matthew J. Lennox, Gerard Tobin, Lisa Goodman, Tina Dueren, Wolfgang Schmitt^*

^*Corresponding author for this work

School of Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a topological blueprint. The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented Cu-II acetate-based MOFs.

Original language	English
Pages (from-to)	3595-3599
Number of pages	5
Journal	Chemistry - A European Journal
Volume	20
Issue number	13
DOIs	https://doi.org/10.1002/chem.201304856
Publication status	Published - 24 Mar 2014

Keywords / Materials (for Non-textual outputs)

coordination chemistry
copper
epitaxy
metal-organic frameworks
supramolecular chemistry
HYDROGEN STORAGE
BUILDING UNITS
GAS-STORAGE
LARGE PORES
SOLIDS
ROBUST
CATALYSIS
CLUSTERS
POLYMER
DESIGN

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10.1002/chem.201304856

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title = "Hetero- Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal- Organic Frameworks with High Surface Areas",

abstract = "A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a topological blueprint. The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented Cu-II acetate-based MOFs.",

keywords = "coordination chemistry, copper, epitaxy, metal-organic frameworks, supramolecular chemistry, HYDROGEN STORAGE, BUILDING UNITS, GAS-STORAGE, LARGE PORES, SOLIDS, ROBUST, CATALYSIS, CLUSTERS, POLYMER, DESIGN",

author = "Nianyong Zhu and Lennox, {Matthew J.} and Gerard Tobin and Lisa Goodman and Tina Dueren and Wolfgang Schmitt",

year = "2014",

month = mar,

day = "24",

doi = "10.1002/chem.201304856",

language = "English",

volume = "20",

pages = "3595--3599",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "13",

}

TY - JOUR

T1 - Hetero- Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal- Organic Frameworks with High Surface Areas

AU - Zhu, Nianyong

AU - Lennox, Matthew J.

AU - Tobin, Gerard

AU - Goodman, Lisa

AU - Dueren, Tina

AU - Schmitt, Wolfgang

PY - 2014/3/24

Y1 - 2014/3/24

N2 - A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a topological blueprint. The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented Cu-II acetate-based MOFs.

AB - A solid-state approach that takes advantage of the ordered 3D arrangement of active secondary building units allows the preparation of new interlocked MOFs that grow hetero-epitaxially on the crystal faces of a precursor phase that acts as a topological blueprint. The synthetic strategy is exemplified by using rigid acetylene-based ligands to produce highly augmented Cu-II acetate-based MOFs.

KW - coordination chemistry

KW - copper

KW - epitaxy

KW - metal-organic frameworks

KW - supramolecular chemistry

KW - HYDROGEN STORAGE

KW - BUILDING UNITS

KW - GAS-STORAGE

KW - LARGE PORES

KW - SOLIDS

KW - ROBUST

KW - CATALYSIS

KW - CLUSTERS

KW - POLYMER

KW - DESIGN

U2 - 10.1002/chem.201304856

DO - 10.1002/chem.201304856

M3 - Article

SN - 0947-6539

VL - 20

SP - 3595

EP - 3599

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 13

ER -

Hetero- Epitaxial Approach by Using Labile Coordination Sites to Prepare Catenated Metal- Organic Frameworks with High Surface Areas

Abstract

Keywords / Materials (for Non-textual outputs)

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