High-spin M2+ carboxylate triangles from the microwave

Constantinos J. Milios; Alessandro Prescimone; J. Sanchez-Benitez; Simon Parsons; Mark Murrie; Euan K. Brechin

doi:10.1021/ic061035o

High-spin M2+ carboxylate triangles from the microwave

Constantinos J. Milios, Alessandro Prescimone, J. Sanchez-Benitez, Simon Parsons, Mark Murrie, Euan K. Brechin

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of M(O2CMe)(2), 4H(2)O (M) Ni, Co) with NaN3 in pyridine/MeOH under microwave irradiation and controlled pressure/temperature leads to the formation of the trimetallic species [M-3-(N-3)(3)(O2CMe)(3)(py)(5)] (M) Ni, 1; Co, 2) in 4 min and in high yields. Both complexes display dominant ferromagnetic interactions and high-spin ground states.

Original language	English
Pages (from-to)	7053-7055
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	18
DOIs	https://doi.org/10.1021/ic061035o
Publication status	Published - 4 Sept 2006

Keywords / Materials (for Non-textual outputs)

INELASTIC NEUTRON-SCATTERING
BULK MAGNETIC-PROPERTIES
SINGLE-MOLECULE MAGNETS
FE-III CLUSTER
EXCHANGE INTERACTIONS
SOLVOTHERMAL SYNTHESIS
COBALT(II) COMPLEXES
DI-2-PYRIDYL KETONE
ASSISTED SYNTHESIS
ENERGY-LEVELS

Access to Document

10.1021/ic061035o

Cite this

@article{ba1d08fed035469586549b20542bb412,

title = "High-spin M2+ carboxylate triangles from the microwave",

abstract = "The reaction of M(O2CMe)(2), 4H(2)O (M) Ni, Co) with NaN3 in pyridine/MeOH under microwave irradiation and controlled pressure/temperature leads to the formation of the trimetallic species [M-3-(N-3)(3)(O2CMe)(3)(py)(5)] (M) Ni, 1; Co, 2) in 4 min and in high yields. Both complexes display dominant ferromagnetic interactions and high-spin ground states.",

keywords = "INELASTIC NEUTRON-SCATTERING, BULK MAGNETIC-PROPERTIES, SINGLE-MOLECULE MAGNETS, FE-III CLUSTER, EXCHANGE INTERACTIONS, SOLVOTHERMAL SYNTHESIS, COBALT(II) COMPLEXES, DI-2-PYRIDYL KETONE, ASSISTED SYNTHESIS, ENERGY-LEVELS",

author = "Milios, \{Constantinos J.\} and Alessandro Prescimone and J. Sanchez-Benitez and Simon Parsons and Mark Murrie and Brechin, \{Euan K.\}",

year = "2006",

month = sep,

day = "4",

doi = "10.1021/ic061035o",

language = "English",

volume = "45",

pages = "7053--7055",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "18",

}

TY - JOUR

T1 - High-spin M2+ carboxylate triangles from the microwave

AU - Milios, Constantinos J.

AU - Prescimone, Alessandro

AU - Sanchez-Benitez, J.

AU - Parsons, Simon

AU - Murrie, Mark

AU - Brechin, Euan K.

PY - 2006/9/4

Y1 - 2006/9/4

N2 - The reaction of M(O2CMe)(2), 4H(2)O (M) Ni, Co) with NaN3 in pyridine/MeOH under microwave irradiation and controlled pressure/temperature leads to the formation of the trimetallic species [M-3-(N-3)(3)(O2CMe)(3)(py)(5)] (M) Ni, 1; Co, 2) in 4 min and in high yields. Both complexes display dominant ferromagnetic interactions and high-spin ground states.

AB - The reaction of M(O2CMe)(2), 4H(2)O (M) Ni, Co) with NaN3 in pyridine/MeOH under microwave irradiation and controlled pressure/temperature leads to the formation of the trimetallic species [M-3-(N-3)(3)(O2CMe)(3)(py)(5)] (M) Ni, 1; Co, 2) in 4 min and in high yields. Both complexes display dominant ferromagnetic interactions and high-spin ground states.

KW - INELASTIC NEUTRON-SCATTERING

KW - BULK MAGNETIC-PROPERTIES

KW - SINGLE-MOLECULE MAGNETS

KW - FE-III CLUSTER

KW - EXCHANGE INTERACTIONS

KW - SOLVOTHERMAL SYNTHESIS

KW - COBALT(II) COMPLEXES

KW - DI-2-PYRIDYL KETONE

KW - ASSISTED SYNTHESIS

KW - ENERGY-LEVELS

U2 - 10.1021/ic061035o

DO - 10.1021/ic061035o

M3 - Article

SN - 0020-1669

VL - 45

SP - 7053

EP - 7055

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 18

ER -

High-spin M2+ carboxylate triangles from the microwave

Abstract

Keywords / Materials (for Non-textual outputs)

Access to Document

Fingerprint

Cite this