Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

Laura Bini; Christian Mueller; Jos Wilting; Lars von Chrzanowski; Anthony L. Spek; Dieter Vogt

doi:10.1021/ja074922e

Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

Laura Bini, Christian Mueller, Jos Wilting, Lars von Chrzanowski, Anthony L. Spek, Dieter Vogt

Research output: Contribution to journal › Article › peer-review

Abstract

A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.

Original language	English
Pages (from-to)	12622-+
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	129
Issue number	42
DOIs	https://doi.org/10.1021/ja074922e
Publication status	Published - 24 Oct 2007

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title = "Highly selective hydrocyanation of butadiene toward 3-pentenenitrile",

abstract = "A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.",

author = "Laura Bini and Christian Mueller and Jos Wilting and {von Chrzanowski}, Lars and Spek, {Anthony L.} and Dieter Vogt",

year = "2007",

month = oct,

day = "24",

doi = "10.1021/ja074922e",

language = "English",

volume = "129",

pages = "12622--+",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "42",

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T1 - Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

AU - Bini, Laura

AU - Mueller, Christian

AU - Wilting, Jos

AU - von Chrzanowski, Lars

AU - Spek, Anthony L.

AU - Vogt, Dieter

PY - 2007/10/24

Y1 - 2007/10/24

N2 - A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.

AB - A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.

U2 - 10.1021/ja074922e

DO - 10.1021/ja074922e

M3 - Article

VL - 129

SP - 12622-+

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 42

ER -

Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

Abstract

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