Hybrid perovskite-like iodobismuthates as low-cost and stable anode materials for lithium-ion battery applications

Kingshuk Roy; Tianyue Li; Satishchandra Ogale; Neil Robertson

doi:10.1039/d0ta07414d

Hybrid perovskite-like iodobismuthates as low-cost and stable anode materials for lithium-ion battery applications

Kingshuk Roy, Tianyue Li, Satishchandra Ogale^*, Neil Robertson

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

We report the electrochemical applications of hybrid iodobismuthates [C₃H₅N₂]₃[Bi₂I₉] (IMB), [C₂H₄N₃S][BiI₄] (ADB) and [C₃H₅N₂S][BiI₄] (ATB), as a new type of environmentally-friendly anode for lithium-ion batteries. The materials show impressive Li-storage capacities along with very good rate capabilities and stability. The excellent properties of ATB, ADB and IMB indicate that further development and optimisation of this new family may be possible by further cation tuning within the series.

Original language	English
Pages (from-to)	2689-2693
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	9
Issue number	5
Early online date	20 Jan 2021
DOIs	https://doi.org/10.1039/d0ta07414d
Publication status	E-pub ahead of print - 20 Jan 2021

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https://pubs.rsc.org/en/content/articlelanding/2021/TA/D0TA07414D#!divAbstract

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title = "Hybrid perovskite-like iodobismuthates as low-cost and stable anode materials for lithium-ion battery applications",

abstract = "We report the electrochemical applications of hybrid iodobismuthates [C3H5N2]3[Bi2I9] (IMB), [C2H4N3S][BiI4] (ADB) and [C3H5N2S][BiI4] (ATB), as a new type of environmentally-friendly anode for lithium-ion batteries. The materials show impressive Li-storage capacities along with very good rate capabilities and stability. The excellent properties of ATB, ADB and IMB indicate that further development and optimisation of this new family may be possible by further cation tuning within the series.",

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T1 - Hybrid perovskite-like iodobismuthates as low-cost and stable anode materials for lithium-ion battery applications

AU - Roy, Kingshuk

AU - Li, Tianyue

AU - Ogale, Satishchandra

AU - Robertson, Neil

PY - 2021/1/20

Y1 - 2021/1/20

N2 - We report the electrochemical applications of hybrid iodobismuthates [C3H5N2]3[Bi2I9] (IMB), [C2H4N3S][BiI4] (ADB) and [C3H5N2S][BiI4] (ATB), as a new type of environmentally-friendly anode for lithium-ion batteries. The materials show impressive Li-storage capacities along with very good rate capabilities and stability. The excellent properties of ATB, ADB and IMB indicate that further development and optimisation of this new family may be possible by further cation tuning within the series.

AB - We report the electrochemical applications of hybrid iodobismuthates [C3H5N2]3[Bi2I9] (IMB), [C2H4N3S][BiI4] (ADB) and [C3H5N2S][BiI4] (ATB), as a new type of environmentally-friendly anode for lithium-ion batteries. The materials show impressive Li-storage capacities along with very good rate capabilities and stability. The excellent properties of ATB, ADB and IMB indicate that further development and optimisation of this new family may be possible by further cation tuning within the series.

U2 - 10.1039/d0ta07414d

DO - 10.1039/d0ta07414d

M3 - Article

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JO - Journal of Materials Chemistry A: materials for energy and sustainability

JF - Journal of Materials Chemistry A: materials for energy and sustainability

SN - 2050-7488

IS - 5

ER -

Hybrid perovskite-like iodobismuthates as low-cost and stable anode materials for lithium-ion battery applications

Abstract

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