Insertion and Substitution Chemistry at the Boron Fourth Position in Charge-Neutral Zwitterionic Tripodal Tris(methimazolyl)borate Ligands

Nicola L. Bell; Gary S. Nichol; Simon Parsons; Fraser White.; Philip Bailey

doi:10.1021/ic202618p

Insertion and Substitution Chemistry at the Boron Fourth Position in Charge-Neutral Zwitterionic Tripodal Tris(methimazolyl)borate Ligands

Nicola L. Bell, Gary S. Nichol, Simon Parsons, Fraser White., Philip Bailey

Research output: Contribution to journal › Article › peer-review

Abstract

A number of new charge-neutral zwitterionic tris(methimazolyl)borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B–N(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate and (cyano)tris(methimazolyl)borate, have also been accessed by this method.

Original language	English
Pages (from-to)	3677-3689
Number of pages	13
Journal	Inorganic Chemistry
Volume	51
Issue number	6
DOIs	https://doi.org/10.1021/ic202618p
Publication status	Published - 19 Mar 2012

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abstract = "A number of new charge-neutral zwitterionic tris(methimazolyl)borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B–N(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate and (cyano)tris(methimazolyl)borate, have also been accessed by this method.",

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AU - Bell, Nicola L.

AU - Nichol, Gary S.

AU - Parsons, Simon

AU - White., Fraser

AU - Bailey, Philip

PY - 2012/3/19

Y1 - 2012/3/19

N2 - A number of new charge-neutral zwitterionic tris(methimazolyl)borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B–N(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate and (cyano)tris(methimazolyl)borate, have also been accessed by this method.

AB - A number of new charge-neutral zwitterionic tris(methimazolyl)borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B–N(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate and (cyano)tris(methimazolyl)borate, have also been accessed by this method.

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U2 - 10.1021/ic202618p

DO - 10.1021/ic202618p

M3 - Article

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JF - Inorganic Chemistry

SN - 0020-1669

IS - 6

ER -

Insertion and Substitution Chemistry at the Boron Fourth Position in Charge-Neutral Zwitterionic Tripodal Tris(methimazolyl)borate Ligands

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