Ion-tagged pi-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid

Patrick S. Baeuerlein; Ian J. S. Fairlamb; Amanda G. Jarvis; Adam F. Lee; Christian Muller; John M. Slattery; Robert J. Thatcher; Dieter Vogt; Adrian C. Whitwood

doi:10.1039/b906823f

Ion-tagged pi-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid

Patrick S. Baeuerlein, Ian J. S. Fairlamb, Amanda G. Jarvis, Adam F. Lee, Christian Muller, John M. Slattery, Robert J. Thatcher, Dieter Vogt, Adrian C. Whitwood

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

Ionic pi-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been "doped" into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.

Original language	English
Pages (from-to)	5734-5736
Number of pages	3
Journal	Chemical Communications
Issue number	38
DOIs	https://doi.org/10.1039/b906823f
Publication status	Published - 2009

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title = "Ion-tagged pi-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid",

abstract = "Ionic pi-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been {"}doped{"} into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.",

author = "Baeuerlein, {Patrick S.} and Fairlamb, {Ian J. S.} and Jarvis, {Amanda G.} and Lee, {Adam F.} and Christian Muller and Slattery, {John M.} and Thatcher, {Robert J.} and Dieter Vogt and Whitwood, {Adrian C.}",

year = "2009",

doi = "10.1039/b906823f",

language = "English",

pages = "5734--5736",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "38",

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T1 - Ion-tagged pi-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid

AU - Baeuerlein, Patrick S.

AU - Fairlamb, Ian J. S.

AU - Jarvis, Amanda G.

AU - Lee, Adam F.

AU - Muller, Christian

AU - Slattery, John M.

AU - Thatcher, Robert J.

AU - Vogt, Dieter

AU - Whitwood, Adrian C.

PY - 2009

Y1 - 2009

N2 - Ionic pi-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been "doped" into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.

AB - Ionic pi-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been "doped" into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.

U2 - 10.1039/b906823f

DO - 10.1039/b906823f

M3 - Article

SN - 1359-7345

SP - 5734

EP - 5736

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Ion-tagged pi-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid

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