Iron-Catalysed Reductive Cross-Coupling of Alkenes

Mark D. Greenhalgh; Stephen P. Thomas

doi:10.1002/cctc.201402076

Iron-Catalysed Reductive Cross-Coupling of Alkenes

Mark D. Greenhalgh, Stephen P. Thomas^*

^*Corresponding author for this work

Research output: Contribution to journal › Editorial › peer-review

Abstract

Iron-catalyzed alkene hydrofunctionalization has been reported by a number of groups using the reaction of unactivated alkenes with sodium borohydride or phenylsilane to give alkyl radical intermediates. Reaction with a range of radical traps has been applied to the formation of carbon–carbon and carbon–heteroatom bonds and used recently for reductive cross-coupling of alkenes. EWG=Electron-withdrawing group.

Original language	English
Pages (from-to)	1520-1522
Journal	ChemCatChe
Volume	6
Issue number	6
Early online date	25 Apr 2014
DOIs	https://doi.org/10.1002/cctc.201402076
Publication status	Published - Jun 2014

Keywords / Materials (for Non-textual outputs)

alkenes
C-C coupling
homogeneous catalysis
iron
radicals
RADICAL CYCLIZATION
UNACTIVATED ALKENES
SODIUM-BOROHYDRIDE
OXYGENATION
OLEFINS
NITROSATION
COMPLEXES
ALCOHOLS
STYRENE
ANALOGS

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10.1002/cctc.201402076

http://onlinelibrary.wiley.com/doi/10.1002/cctc.201402076/full

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@article{90adba8f33964e16be987d32d3752f7d,

title = "Iron-Catalysed Reductive Cross-Coupling of Alkenes",

abstract = "Iron-catalyzed alkene hydrofunctionalization has been reported by a number of groups using the reaction of unactivated alkenes with sodium borohydride or phenylsilane to give alkyl radical intermediates. Reaction with a range of radical traps has been applied to the formation of carbon–carbon and carbon–heteroatom bonds and used recently for reductive cross-coupling of alkenes. EWG=Electron-withdrawing group.",

keywords = "alkenes, C-C coupling, homogeneous catalysis, iron, radicals, RADICAL CYCLIZATION, UNACTIVATED ALKENES, SODIUM-BOROHYDRIDE, OXYGENATION, OLEFINS, NITROSATION, COMPLEXES, ALCOHOLS, STYRENE, ANALOGS",

author = "Greenhalgh, {Mark D.} and Thomas, {Stephen P.}",

year = "2014",

month = jun,

doi = "10.1002/cctc.201402076",

language = "English",

volume = "6",

pages = "1520--1522",

journal = "ChemCatChe",

issn = "1867-3880",

publisher = "Wiley-VCH",

number = "6",

}

TY - JOUR

T1 - Iron-Catalysed Reductive Cross-Coupling of Alkenes

AU - Greenhalgh, Mark D.

AU - Thomas, Stephen P.

PY - 2014/6

Y1 - 2014/6

N2 - Iron-catalyzed alkene hydrofunctionalization has been reported by a number of groups using the reaction of unactivated alkenes with sodium borohydride or phenylsilane to give alkyl radical intermediates. Reaction with a range of radical traps has been applied to the formation of carbon–carbon and carbon–heteroatom bonds and used recently for reductive cross-coupling of alkenes. EWG=Electron-withdrawing group.

AB - Iron-catalyzed alkene hydrofunctionalization has been reported by a number of groups using the reaction of unactivated alkenes with sodium borohydride or phenylsilane to give alkyl radical intermediates. Reaction with a range of radical traps has been applied to the formation of carbon–carbon and carbon–heteroatom bonds and used recently for reductive cross-coupling of alkenes. EWG=Electron-withdrawing group.

KW - alkenes

KW - C-C coupling

KW - homogeneous catalysis

KW - iron

KW - radicals

KW - RADICAL CYCLIZATION

KW - UNACTIVATED ALKENES

KW - SODIUM-BOROHYDRIDE

KW - OXYGENATION

KW - OLEFINS

KW - NITROSATION

KW - COMPLEXES

KW - ALCOHOLS

KW - STYRENE

KW - ANALOGS

U2 - 10.1002/cctc.201402076

DO - 10.1002/cctc.201402076

M3 - Editorial

SN - 1867-3880

VL - 6

SP - 1520

EP - 1522

JO - ChemCatChe

JF - ChemCatChe

IS - 6

ER -

Iron-Catalysed Reductive Cross-Coupling of Alkenes

Abstract

Keywords / Materials (for Non-textual outputs)

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