Iron-catalyzed dehydropolymerization: A convenient route to poly(phosphinoboranes) with molecular-weight control

André Schäfer; Titel Jurca; Joshua Turner; James R. Vance; Kajin Lee; Van An Du; Mairi F. Haddow; George R. Whittell; Ian Manners

doi:10.1002/anie.201411957

Iron-catalyzed dehydropolymerization: A convenient route to poly(phosphinoboranes) with molecular-weight control

André Schäfer, Titel Jurca, Joshua Turner, James R. Vance, Kajin Lee, Van An Du, Mairi F. Haddow, George R. Whittell, Ian Manners

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.

Original language	English
Pages (from-to)	4836-4841
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	16
Early online date	7 Apr 2015
DOIs	https://doi.org/10.1002/anie.201411957
Publication status	Published - 13 Apr 2015

Keywords / Materials (for Non-textual outputs)

dehydrocoupling
dehydropolymerization
iron catalysis
phosphine-borane adducts
poly(phosphinoboranes)

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10.1002/anie.201411957

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title = "Iron-catalyzed dehydropolymerization: A convenient route to poly(phosphinoboranes) with molecular-weight control",

abstract = "The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.",

keywords = "dehydrocoupling, dehydropolymerization, iron catalysis, phosphine-borane adducts, poly(phosphinoboranes)",

author = "Andr{\'e} Sch{\"a}fer and Titel Jurca and Joshua Turner and Vance, \{James R.\} and Kajin Lee and Du, \{Van An\} and Haddow, \{Mairi F.\} and Whittell, \{George R.\} and Ian Manners",

note = "Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

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doi = "10.1002/anie.201411957",

language = "English",

volume = "54",

pages = "4836--4841",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Iron-catalyzed dehydropolymerization

T2 - A convenient route to poly(phosphinoboranes) with molecular-weight control

AU - Schäfer, André

AU - Jurca, Titel

AU - Turner, Joshua

AU - Vance, James R.

AU - Lee, Kajin

AU - Du, Van An

AU - Haddow, Mairi F.

AU - Whittell, George R.

AU - Manners, Ian

PY - 2015/4/13

Y1 - 2015/4/13

N2 - The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.

AB - The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.

KW - dehydrocoupling

KW - dehydropolymerization

KW - iron catalysis

KW - phosphine-borane adducts

KW - poly(phosphinoboranes)

U2 - 10.1002/anie.201411957

DO - 10.1002/anie.201411957

M3 - Article

AN - SCOPUS:84926434214

SN - 1433-7851

VL - 54

SP - 4836

EP - 4841

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16

ER -

Iron-catalyzed dehydropolymerization: A convenient route to poly(phosphinoboranes) with molecular-weight control

Abstract

Keywords / Materials (for Non-textual outputs)

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