Isotopic desymmetrization in the study of homogeneous catalysis

IJS Fairlamb; GC Lloyd-Jones; A Martorell; M Murray; SC Stephen; PM Tomlin

Isotopic desymmetrization in the study of homogeneous catalysis

IJS Fairlamb, GC Lloyd-Jones, A Martorell, M Murray^*, SC Stephen, PM Tomlin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

NMR studies on isotopically desymmetrized ligands and substrates have been used to demonstrate and investigate an apparent "memory effect" in palladium-catalysed nucleophilic substitution at allylic centres. The explanation for this "memory effect" is shown to be the participation of both monomeric and oligomeric complexes, with different reaction rates.

Original language	English
Pages (from-to)	907-910
Number of pages	4
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	179
Issue number	4-5
Publication status	Published - 2004
Event	10th International Symposium on Inorganic Ring Systems (IRIS 10) - Burlington, United Kingdom Duration: 17 Aug 2003 → 22 Aug 2003

Keywords / Materials (for Non-textual outputs)

diphosphine ligands
isotopically desymmetrized ligands
NMR

Cite this

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title = "Isotopic desymmetrization in the study of homogeneous catalysis",

abstract = "NMR studies on isotopically desymmetrized ligands and substrates have been used to demonstrate and investigate an apparent {"}memory effect{"} in palladium-catalysed nucleophilic substitution at allylic centres. The explanation for this {"}memory effect{"} is shown to be the participation of both monomeric and oligomeric complexes, with different reaction rates.",

keywords = "diphosphine ligands, isotopically desymmetrized ligands, NMR",

author = "IJS Fairlamb and GC Lloyd-Jones and A Martorell and M Murray and SC Stephen and PM Tomlin",

year = "2004",

language = "English",

volume = "179",

pages = "907--910",

journal = "Phosphorus, Sulfur, and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor & Francis",

number = "4-5",

note = "10th International Symposium on Inorganic Ring Systems (IRIS 10) ; Conference date: 17-08-2003 Through 22-08-2003",

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TY - JOUR

T1 - Isotopic desymmetrization in the study of homogeneous catalysis

AU - Fairlamb, IJS

AU - Lloyd-Jones, GC

AU - Martorell, A

AU - Murray, M

AU - Stephen, SC

AU - Tomlin, PM

PY - 2004

Y1 - 2004

N2 - NMR studies on isotopically desymmetrized ligands and substrates have been used to demonstrate and investigate an apparent "memory effect" in palladium-catalysed nucleophilic substitution at allylic centres. The explanation for this "memory effect" is shown to be the participation of both monomeric and oligomeric complexes, with different reaction rates.

AB - NMR studies on isotopically desymmetrized ligands and substrates have been used to demonstrate and investigate an apparent "memory effect" in palladium-catalysed nucleophilic substitution at allylic centres. The explanation for this "memory effect" is shown to be the participation of both monomeric and oligomeric complexes, with different reaction rates.

KW - diphosphine ligands

KW - isotopically desymmetrized ligands

KW - NMR

M3 - Article

SN - 1042-6507

VL - 179

SP - 907

EP - 910

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 4-5

T2 - 10th International Symposium on Inorganic Ring Systems (IRIS 10)

Y2 - 17 August 2003 through 22 August 2003

ER -

Isotopic desymmetrization in the study of homogeneous catalysis

Abstract

Keywords / Materials (for Non-textual outputs)

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