Lead(IV) chloride at 150 K

I J  Maley; S  Parsons; C R  Pulham

doi:10.1107/S1600536802015064

Lead(IV) chloride at 150 K

I J Maley, S Parsons, C R Pulham

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Lead(IV) chloride, PbCl4, is a volatile air-sensitive liquid under ambient conditions. The crystal structure consists of tetrahedral molecules residing on crystallographic twofold axes, with no intermolecular interactions within the sum of van der Waals radii. Unlike the lighter Group 14 analogues, which are based on hexagonal close packing of Cl atoms, the Cl atoms in PbCl4 form a cubic close-packed array.

Original language	English
Pages (from-to)	I79-I81
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	58
DOIs	https://doi.org/10.1107/S1600536802015064
Publication status	Published - Sept 2002

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title = "Lead(IV) chloride at 150 K",

abstract = "Lead(IV) chloride, PbCl4, is a volatile air-sensitive liquid under ambient conditions. The crystal structure consists of tetrahedral molecules residing on crystallographic twofold axes, with no intermolecular interactions within the sum of van der Waals radii. Unlike the lighter Group 14 analogues, which are based on hexagonal close packing of Cl atoms, the Cl atoms in PbCl4 form a cubic close-packed array.",

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AU - Maley, I J

AU - Parsons, S

AU - Pulham, C R

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AB - Lead(IV) chloride, PbCl4, is a volatile air-sensitive liquid under ambient conditions. The crystal structure consists of tetrahedral molecules residing on crystallographic twofold axes, with no intermolecular interactions within the sum of van der Waals radii. Unlike the lighter Group 14 analogues, which are based on hexagonal close packing of Cl atoms, the Cl atoms in PbCl4 form a cubic close-packed array.

U2 - 10.1107/S1600536802015064

DO - 10.1107/S1600536802015064

M3 - Article

SN - 1600-5368

VL - 58

SP - I79-I81

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

Lead(IV) chloride at 150 K

Abstract

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