Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

David m. Kitcatt; Eva Pogacar; Le Mi; Simon Nicolle; Ai-Lan Lee

doi:10.1021/acs.joc.4c02163

Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

David m. Kitcatt, Eva Pogacar, Le Mi, Simon Nicolle, Ai-Lan Lee

Research output: Contribution to journal › Article › peer-review

Abstract

Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

Original language	English
Pages (from-to)	16055-16059
Journal	The Journal of Organic Chemistry (JOC)
Volume	89
Issue number	21
Early online date	22 Oct 2024
DOIs	https://doi.org/10.1021/acs.joc.4c02163
Publication status	E-pub ahead of print - 22 Oct 2024

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https://pubs.acs.org/doi/10.1021/acs.joc.4c02163Licence: Creative Commons: Attribution (CC-BY)

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title = "Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst",

abstract = "Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.",

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AU - Kitcatt, David m.

AU - Pogacar, Eva

AU - Mi, Le

AU - Nicolle, Simon

AU - Lee, Ai-Lan

PY - 2024/10/22

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N2 - Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

AB - Previous light-mediated approaches to the direct decarboxylative Giese aroylation reaction have mainly relied on the use of a photocatalyst and a reductive quenching pathway. By exploiting a mechanistically distinct oxidative protocol, we have successfully developed a photocatalyst-free, light-mediated direct Giese aroylation methodology.

U2 - 10.1021/acs.joc.4c02163

DO - 10.1021/acs.joc.4c02163

M3 - Article

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JO - The Journal of Organic Chemistry (JOC)

JF - The Journal of Organic Chemistry (JOC)

IS - 21

ER -

Light-Mediated Direct Decarboxylative Giese Aroylations without a Photocatalyst

Abstract

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