Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes

K. Mason; J. Chang; E. Garlatti; A. Prescimone; S. Yoshii; H. Nojiri; J. Schnack; P. A. Tasker; S. Carretta; E. K. Brechin

doi:10.1039/c1cc11146a

Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes

K. Mason, J. Chang, E. Garlatti, A. Prescimone, S. Yoshii, H. Nojiri, J. Schnack, P. A. Tasker, S. Carretta, E. K. Brechin

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

The use of "double-headed" phenolic oximes produces a trigonal antiprismatic [Fe-3(III)](2) cluster with an "internal cavity" filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

Original language	English
Pages (from-to)	6018-6020
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	21
DOIs	https://doi.org/10.1039/c1cc11146a
Publication status	Published - 2011

Keywords / Materials (for Non-textual outputs)

SINGLE-MOLECULE MAGNET
SALICYLALDOXIME
HEXANUCLEAR
COMPLEXES
CHEMISTRY

Access to Document

10.1039/c1cc11146a

Cite this

@article{c10d6c714f774457a383ef047418e460,

title = "Linking [Fe-3(III)] triangles with {"}double-headed{"} phenolic oximes",

abstract = "The use of {"}double-headed{"} phenolic oximes produces a trigonal antiprismatic [Fe-3(III)](2) cluster with an {"}internal cavity{"} filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.",

keywords = "SINGLE-MOLECULE MAGNET, SALICYLALDOXIME, HEXANUCLEAR, COMPLEXES, CHEMISTRY",

author = "K. Mason and J. Chang and E. Garlatti and A. Prescimone and S. Yoshii and H. Nojiri and J. Schnack and Tasker, {P. A.} and S. Carretta and Brechin, {E. K.}",

year = "2011",

doi = "10.1039/c1cc11146a",

language = "English",

volume = "47",

pages = "6018--6020",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

}

TY - JOUR

T1 - Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes

AU - Mason, K.

AU - Chang, J.

AU - Garlatti, E.

AU - Prescimone, A.

AU - Yoshii, S.

AU - Nojiri, H.

AU - Schnack, J.

AU - Tasker, P. A.

AU - Carretta, S.

AU - Brechin, E. K.

PY - 2011

Y1 - 2011

N2 - The use of "double-headed" phenolic oximes produces a trigonal antiprismatic [Fe-3(III)](2) cluster with an "internal cavity" filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

AB - The use of "double-headed" phenolic oximes produces a trigonal antiprismatic [Fe-3(III)](2) cluster with an "internal cavity" filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

KW - SINGLE-MOLECULE MAGNET

KW - SALICYLALDOXIME

KW - HEXANUCLEAR

KW - COMPLEXES

KW - CHEMISTRY

UR - http://www.scopus.com/inward/record.url?scp=79956151496&partnerID=8YFLogxK

U2 - 10.1039/c1cc11146a

DO - 10.1039/c1cc11146a

M3 - Article

SN - 1359-7345

VL - 47

SP - 6018

EP - 6020

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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Other files and links

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EPR characterization of molecular magneto-structural correlations under pressure

Pressure Sensitive Complexformation based on self assembling ligands

Advanced Fellowship : Novel Single-Molecule Magnets

Cite this

Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

Access to Document

Other files and links

Fingerprint

Projects

EPR characterization of molecular magneto-structural correlations under pressure

Pressure Sensitive Complexformation based on self assembling ligands

Advanced Fellowship : Novel Single-Molecule Magnets

Cite this