Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides

Kun-lang Ji; Elena Solana-madruga; Angel M. Arevalo-lopez; Pascal Manuel; Clemens Ritter; Anatoliy Senyshyn; J. Paul Attfield

doi:10.1039/C8CC07556E

Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides

Kun-lang Ji, Elena Solana-madruga, Angel M. Arevalo-lopez, Pascal Manuel, Clemens Ritter, Anatoliy Senyshyn, J. Paul Attfield

School of Chemistry

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Abstract / Description of output

The new phase Co2ScSbO6 and Ni2-xCoxScSbO6 solid solutions adopt the polar Ni3TeO6-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.

Original language	English
Journal	Chemical Communications
Early online date	15 Oct 2018
DOIs	https://doi.org/10.1039/C8CC07556E
Publication status	E-pub ahead of print - 15 Oct 2018

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10.1039/C8CC07556E

20182910 Attfield Ni2-xCoxScSbO6-resubAccepted author manuscript, 947 KBLicence: Creative Commons: Attribution Non-Commercial (CC-BY-NC)
c8cc07556eFinal published version, 2.41 MBLicence: Creative Commons: Attribution Non-Commercial (CC-BY-NC)

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Cite this

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title = "Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides",

abstract = "The new phase Co2ScSbO6 and Ni2-xCoxScSbO6 solid solutions adopt the polar Ni3TeO6-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.",

author = "Kun-lang Ji and Elena Solana-madruga and Arevalo-lopez, {Angel M.} and Pascal Manuel and Clemens Ritter and Anatoliy Senyshyn and Attfield, {J. Paul}",

year = "2018",

month = oct,

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doi = "10.1039/C8CC07556E",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides

AU - Ji, Kun-lang

AU - Solana-madruga, Elena

AU - Arevalo-lopez, Angel M.

AU - Manuel, Pascal

AU - Ritter, Clemens

AU - Senyshyn, Anatoliy

AU - Attfield, J. Paul

PY - 2018/10/15

Y1 - 2018/10/15

N2 - The new phase Co2ScSbO6 and Ni2-xCoxScSbO6 solid solutions adopt the polar Ni3TeO6-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.

AB - The new phase Co2ScSbO6 and Ni2-xCoxScSbO6 solid solutions adopt the polar Ni3TeO6-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.

U2 - 10.1039/C8CC07556E

DO - 10.1039/C8CC07556E

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides

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