Low-dimensional magnetism in calcium nitridonickelate(II) Ca2NiN2

Simon David Kloß, Paul Attfield

Research output: Contribution to journalArticlepeer-review

Abstract

Calcium nitridonickelate(II) Ca2NiN2 has been prepared through a high-temperature and high-pressure azide-mediated redox reaction, demonstrating that this method can stabilise nitrides of late transition metals in relatively high oxidation states. Ca2NiN2 crystallizes in the Na2HgO2 structure type and displays low-dimensional antiferromagnetic ordering of Ni2+ spins.
Original languageEnglish
JournalChemical Communications
Early online date13 Sep 2021
DOIs
Publication statusE-pub ahead of print - 13 Sep 2021

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