Low-valent uranium iodides: Straightforward solution syntheses of Ul(3) and Ul(4) etherates

Christopher D. Carmichael; Natalie A. Jones; Polly L. Arnold

doi:10.1021/hc801138e

Low-valent uranium iodides: Straightforward solution syntheses of Ul(3) and Ul(4) etherates

Christopher D. Carmichael, Natalie A. Jones, Polly L. Arnold

Research output: Contribution to journal › Article › peer-review

Abstract

Uranium turnings react with elemental iodine in diethyl ether at room temperature, with sonication and/or stirring, over a period of days to afford Ul(3), Ul(4)(OEt2)(2), or Ul(4)(OBu2n) depending on the stoichiometry or ether solvent. This is the first room temperature, and thus safe and convenient, synthesis of Ul(3).

Original language	English
Pages (from-to)	8577-8579
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	19
DOIs	https://doi.org/10.1021/hc801138e
Publication status	Published - 6 Oct 2008

Keywords

CRYSTAL-STRUCTURES
TRIVALENT URANIUM
DIETHYL-ETHER
CHEMISTRY
COMPLEXES
TRIIODIDE
LA
DINITROGEN
REDUCTION
NEPTUNIUM

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title = "Low-valent uranium iodides: Straightforward solution syntheses of Ul(3) and Ul(4) etherates",

abstract = "Uranium turnings react with elemental iodine in diethyl ether at room temperature, with sonication and/or stirring, over a period of days to afford Ul(3), Ul(4)(OEt2)(2), or Ul(4)(OBu2n) depending on the stoichiometry or ether solvent. This is the first room temperature, and thus safe and convenient, synthesis of Ul(3).",

keywords = "CRYSTAL-STRUCTURES, TRIVALENT URANIUM, DIETHYL-ETHER, CHEMISTRY, COMPLEXES, TRIIODIDE, LA, DINITROGEN, REDUCTION, NEPTUNIUM",

author = "Carmichael, {Christopher D.} and Jones, {Natalie A.} and Arnold, {Polly L.}",

year = "2008",

month = oct,

day = "6",

doi = "10.1021/hc801138e",

language = "English",

volume = "47",

pages = "8577--8579",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "19",

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T1 - Low-valent uranium iodides: Straightforward solution syntheses of Ul(3) and Ul(4) etherates

AU - Carmichael, Christopher D.

AU - Jones, Natalie A.

AU - Arnold, Polly L.

PY - 2008/10/6

Y1 - 2008/10/6

N2 - Uranium turnings react with elemental iodine in diethyl ether at room temperature, with sonication and/or stirring, over a period of days to afford Ul(3), Ul(4)(OEt2)(2), or Ul(4)(OBu2n) depending on the stoichiometry or ether solvent. This is the first room temperature, and thus safe and convenient, synthesis of Ul(3).

AB - Uranium turnings react with elemental iodine in diethyl ether at room temperature, with sonication and/or stirring, over a period of days to afford Ul(3), Ul(4)(OEt2)(2), or Ul(4)(OBu2n) depending on the stoichiometry or ether solvent. This is the first room temperature, and thus safe and convenient, synthesis of Ul(3).

KW - CRYSTAL-STRUCTURES

KW - TRIVALENT URANIUM

KW - DIETHYL-ETHER

KW - CHEMISTRY

KW - COMPLEXES

KW - TRIIODIDE

KW - LA

KW - DINITROGEN

KW - REDUCTION

KW - NEPTUNIUM

U2 - 10.1021/hc801138e

DO - 10.1021/hc801138e

M3 - Article

VL - 47

SP - 8577

EP - 8579

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 19

ER -

Low-valent uranium iodides: Straightforward solution syntheses of Ul(3) and Ul(4) etherates

Abstract

Keywords

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