Mass-resolved multiphoton ionization spectroscopy of jet-cooled Cl-2- .2. The (2+1) REMPI spectrum between 76000 and 90000 cm(-1)

MSN AlKahali*, RJ Donovan, KP Lawley, T Ridley

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The (2 + 1) resonance-enhanced multiphoton ionization (REMPI) spectrum of Cl-2 has been recorded between 76 000 and 90 000 cm(-1). The origins of twenty Rydberg states are located, with the s series (4s - 8s) generally exhibiting four Omega components and the d series (3d-5d) two components for each value of n. Vibronic coupling between the beta(1(g)) ion-pair state and the 3d and 4d (Omega = 1) states is pronounced, necessitating the use of mass resolved REMPI for the analysis of these vibronically mixed states. (C) 1996 American Institute of Physics.

Original languageEnglish
Pages (from-to)1833-1838
Number of pages6
JournalThe Journal of Chemical Physics
Volume104
Issue number5
DOIs
Publication statusPublished - 1 Feb 1996

Keywords

  • ELECTRON-ENERGY LOSS
  • CHLORINE

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