Abstract
The (2 + 1) resonance-enhanced multiphoton ionization (REMPI) spectrum of Cl-2 has been recorded between 76 000 and 90 000 cm(-1). The origins of twenty Rydberg states are located, with the s series (4s - 8s) generally exhibiting four Omega components and the d series (3d-5d) two components for each value of n. Vibronic coupling between the beta(1(g)) ion-pair state and the 3d and 4d (Omega = 1) states is pronounced, necessitating the use of mass resolved REMPI for the analysis of these vibronically mixed states. (C) 1996 American Institute of Physics.
Original language | English |
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Pages (from-to) | 1833-1838 |
Number of pages | 6 |
Journal | The Journal of Chemical Physics |
Volume | 104 |
Issue number | 5 |
DOIs | |
Publication status | Published - 1 Feb 1996 |
Keywords
- ELECTRON-ENERGY LOSS
- CHLORINE