Mass-resolved multiphoton ionization spectroscopy of jet-cooled Cl-2- .2. The (2+1) REMPI spectrum between 76000 and 90000 cm(-1)

MSN AlKahali; RJ Donovan; KP Lawley; T Ridley

doi:10.1063/1.470980

Mass-resolved multiphoton ionization spectroscopy of jet-cooled Cl-2- .2. The (2+1) REMPI spectrum between 76000 and 90000 cm(-1)

MSN AlKahali^*, RJ Donovan, KP Lawley, T Ridley

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The (2 + 1) resonance-enhanced multiphoton ionization (REMPI) spectrum of Cl-2 has been recorded between 76 000 and 90 000 cm(-1). The origins of twenty Rydberg states are located, with the s series (4s - 8s) generally exhibiting four Omega components and the d series (3d-5d) two components for each value of n. Vibronic coupling between the beta(1(g)) ion-pair state and the 3d and 4d (Omega = 1) states is pronounced, necessitating the use of mass resolved REMPI for the analysis of these vibronically mixed states. (C) 1996 American Institute of Physics.

Original language	English
Pages (from-to)	1833-1838
Number of pages	6
Journal	The Journal of Chemical Physics
Volume	104
Issue number	5
DOIs	https://doi.org/10.1063/1.470980
Publication status	Published - 1 Feb 1996

Keywords

ELECTRON-ENERGY LOSS
CHLORINE

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abstract = "The (2 + 1) resonance-enhanced multiphoton ionization (REMPI) spectrum of Cl-2 has been recorded between 76 000 and 90 000 cm(-1). The origins of twenty Rydberg states are located, with the s series (4s - 8s) generally exhibiting four Omega components and the d series (3d-5d) two components for each value of n. Vibronic coupling between the beta(1(g)) ion-pair state and the 3d and 4d (Omega = 1) states is pronounced, necessitating the use of mass resolved REMPI for the analysis of these vibronically mixed states. (C) 1996 American Institute of Physics.",

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AU - AlKahali, MSN

AU - Donovan, RJ

AU - Lawley, KP

AU - Ridley, T

PY - 1996/2/1

Y1 - 1996/2/1

N2 - The (2 + 1) resonance-enhanced multiphoton ionization (REMPI) spectrum of Cl-2 has been recorded between 76 000 and 90 000 cm(-1). The origins of twenty Rydberg states are located, with the s series (4s - 8s) generally exhibiting four Omega components and the d series (3d-5d) two components for each value of n. Vibronic coupling between the beta(1(g)) ion-pair state and the 3d and 4d (Omega = 1) states is pronounced, necessitating the use of mass resolved REMPI for the analysis of these vibronically mixed states. (C) 1996 American Institute of Physics.

AB - The (2 + 1) resonance-enhanced multiphoton ionization (REMPI) spectrum of Cl-2 has been recorded between 76 000 and 90 000 cm(-1). The origins of twenty Rydberg states are located, with the s series (4s - 8s) generally exhibiting four Omega components and the d series (3d-5d) two components for each value of n. Vibronic coupling between the beta(1(g)) ion-pair state and the 3d and 4d (Omega = 1) states is pronounced, necessitating the use of mass resolved REMPI for the analysis of these vibronically mixed states. (C) 1996 American Institute of Physics.

KW - ELECTRON-ENERGY LOSS

KW - CHLORINE

U2 - 10.1063/1.470980

DO - 10.1063/1.470980

M3 - Article

VL - 104

SP - 1833

EP - 1838

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

SN - 0021-9606

IS - 5

ER -

Mass-resolved multiphoton ionization spectroscopy of jet-cooled Cl-2- .2. The (2+1) REMPI spectrum between 76000 and 90000 cm(-1)

Abstract

Keywords

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