Metal-directed ring-expansion in Schiff-base polypyrrolic macrocycles

G Givaja, A J Blake, C Wilson, M Schroder, J B Love

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction between a [2 + 2] Schiff-base porphyrin analogue and zinc acetate results in the unusual formation of an enlarged [3 + 3] macrocycle that is stabilised by metal coordination and intramolecular hydrogen-bonding interactions.

Original languageEnglish
Pages (from-to)4423-4425
Number of pages3
JournalChemical Communications
Issue number35
DOIs
Publication statusPublished - 2005

Keywords

  • COMPLEXES
  • PORPHYRINS
  • CRYSTAL
  • LIGAND

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