Metamagnetic behaviour in a new Cu(II)Re(IV) chain based on the hexachlororhenate(IV) anion

José Martínez-Lillo; John Kong; Wdeson P Barros; Juan Faus; Miguel Julve; Euan K Brechin

doi:10.1039/c4cc01564a

Metamagnetic behaviour in a new Cu(II)Re(IV) chain based on the hexachlororhenate(IV) anion

José Martínez-Lillo, John Kong, Wdeson P Barros, Juan Faus, Miguel Julve, Euan K Brechin

Research output: Contribution to journal › Article › peer-review

Abstract

A new chloro-bridged heterobimetallic Cu(ii)Re(iv) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (·MeCN) has been prepared and magnetostructurally characterised. Compound is the first example of the [Re(IV)Cl6](2-) anion acting as a metalloligand towards a paramagnetic metal ion.

Original language	English
Article number	50
Pages (from-to)	5840-5842
Journal	Chemical Communications
Volume	2014
Issue number	44
Early online date	8 Apr 2014
DOIs	https://doi.org/10.1039/c4cc01564a
Publication status	Published - 23 Apr 2014

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10.1039/c4cc01564a

Revised_ManuscriptAccepted author manuscript, 7.17 MB

Molecular Magnets: From Cages to Supramolecular Assemblies
Brechin, E. (Principal Investigator)
EPSRC
1/10/13 → 30/09/16
Project: Research

Cite this

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abstract = "A new chloro-bridged heterobimetallic Cu(ii)Re(iv) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (·MeCN) has been prepared and magnetostructurally characterised. Compound is the first example of the [Re(IV)Cl6](2-) anion acting as a metalloligand towards a paramagnetic metal ion.",

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AU - Martínez-Lillo, José

AU - Kong, John

AU - Barros, Wdeson P

AU - Faus, Juan

AU - Julve, Miguel

AU - Brechin, Euan K

PY - 2014/4/23

Y1 - 2014/4/23

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AB - A new chloro-bridged heterobimetallic Cu(ii)Re(iv) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (·MeCN) has been prepared and magnetostructurally characterised. Compound is the first example of the [Re(IV)Cl6](2-) anion acting as a metalloligand towards a paramagnetic metal ion.

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DO - 10.1039/c4cc01564a

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SP - 5840

EP - 5842

JO - Chemical Communications

JF - Chemical Communications

IS - 44

M1 - 50

ER -

Metamagnetic behaviour in a new Cu(II)Re(IV) chain based on the hexachlororhenate(IV) anion

Abstract

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Molecular Magnets: From Cages to Supramolecular Assemblies

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