Metamagnetic behaviour in a new Cu(II)Re(IV) chain based on the hexachlororhenate(IV) anion

José Martínez-Lillo, John Kong, Wdeson P Barros, Juan Faus, Miguel Julve, Euan K Brechin

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

A new chloro-bridged heterobimetallic Cu(ii)Re(iv) chain of formula {Cu(pyim)(Him)2ReCl6}n·MeCN (·MeCN) has been prepared and magnetostructurally characterised. Compound is the first example of the [Re(IV)Cl6](2-) anion acting as a metalloligand towards a paramagnetic metal ion.

Original languageEnglish
Article number50
Pages (from-to)5840-5842
JournalChemical Communications
Volume2014
Issue number44
Early online date8 Apr 2014
DOIs
Publication statusPublished - 23 Apr 2014

Fingerprint

Dive into the research topics of 'Metamagnetic behaviour in a new Cu(II)Re(IV) chain based on the hexachlororhenate(IV) anion'. Together they form a unique fingerprint.

Cite this