Metastable Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity

Elena Madrid, Yuanyang Rong, Mariolino Carta, Neil B. McKeown*, Richard Malpass-Evans, Gary A. Attard, Tomos J. Clarke, Stuart H. Taylor, Yi-Tao Long, Frank Marken

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Troger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.

Original languageEnglish
Pages (from-to)10751-10754
Number of pages4
JournalAngewandte Chemie International Edition
Volume53
Issue number40
Early online date11 Aug 2014
DOIs
Publication statusPublished - 26 Sep 2014

Keywords

  • diodes
  • fuel cells
  • membranes
  • polymers
  • RECTIFYING PROPERTIES
  • TRANSISTORS
  • MEMBRANES
  • PIM-1
  • FILMS

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