Metastable Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity

Elena Madrid; Yuanyang Rong; Mariolino Carta; Neil B. McKeown; Richard Malpass-Evans; Gary A. Attard; Tomos J. Clarke; Stuart H. Taylor; Yi-Tao Long; Frank Marken

doi:10.1002/anie.201405755

Metastable Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity

Elena Madrid, Yuanyang Rong, Mariolino Carta, Neil B. McKeown^*, Richard Malpass-Evans, Gary A. Attard, Tomos J. Clarke, Stuart H. Taylor, Yi-Tao Long, Frank Marken

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Troger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.

Original language	English
Pages (from-to)	10751-10754
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	53
Issue number	40
Early online date	11 Aug 2014
DOIs	https://doi.org/10.1002/anie.201405755
Publication status	Published - 26 Sept 2014

Keywords / Materials (for Non-textual outputs)

diodes
fuel cells
membranes
polymers
RECTIFYING PROPERTIES
TRANSISTORS
MEMBRANES
PIM-1
FILMS

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10.1002/anie.201405755

http://onlinelibrary.wiley.com/doi/10.1002/anie.201405755/full

Neil McKeown
- neil.mckeowned.acuk
- School of Chemistry - Crawford Tercentenary Chair of Chemistry
- EaStCHEM
Person: Academic: Research Active

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title = "Metastable Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity",

abstract = "A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Troger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.",

keywords = "diodes, fuel cells, membranes, polymers, RECTIFYING PROPERTIES, TRANSISTORS, MEMBRANES, PIM-1, FILMS",

author = "Elena Madrid and Yuanyang Rong and Mariolino Carta and McKeown, \{Neil B.\} and Richard Malpass-Evans and Attard, \{Gary A.\} and Clarke, \{Tomos J.\} and Taylor, \{Stuart H.\} and Yi-Tao Long and Frank Marken",

year = "2014",

month = sep,

day = "26",

doi = "10.1002/anie.201405755",

language = "English",

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journal = "Angewandte Chemie International Edition",

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T1 - Metastable Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity

AU - Madrid, Elena

AU - Rong, Yuanyang

AU - Carta, Mariolino

AU - McKeown, Neil B.

AU - Malpass-Evans, Richard

AU - Attard, Gary A.

AU - Clarke, Tomos J.

AU - Taylor, Stuart H.

AU - Long, Yi-Tao

AU - Marken, Frank

PY - 2014/9/26

Y1 - 2014/9/26

N2 - A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Troger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.

AB - A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Troger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.

KW - diodes

KW - fuel cells

KW - membranes

KW - polymers

KW - RECTIFYING PROPERTIES

KW - TRANSISTORS

KW - MEMBRANES

KW - PIM-1

KW - FILMS

U2 - 10.1002/anie.201405755

DO - 10.1002/anie.201405755

M3 - Article

SN - 1433-7851

VL - 53

SP - 10751

EP - 10754

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 40

ER -

Metastable Ionic Diodes Derived from an Amine-Based Polymer of Intrinsic Microporosity

Abstract

Keywords / Materials (for Non-textual outputs)

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Neil McKeown

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