New polynuclear nickel complexes with a variety of pyridonate and carboxylate ligands

Alexander J. Blake, Euan K. Brechin, Arnaud Codron, Robert O. Gould, Craig M. Grant, Simon Parsons, Jeremy M. Rawson, Richard E.P. Winpenny*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A general synthetic strategy for making, and structures and some properties of, several new polynuclear nickel complexes of pyridonate ligands are reported: these complexes include a linear trinuclear complex [Ni 3(chp)4(O2CMe)2(MeOH)6], a tetranuclear cubane [Ni4(OMe)4(η-chp)(chp) 3(MeOH)7] and two undecanuclear complexes [Ni 11(μ-OH)6(O2CMe)6(mhp) 9(H2O)3]2[CO3] and [Ni113-OH)6(O2CMe) 7(mhp)9(Hmhp)2] (Hchp and Hmhp=6-chloro- and 6-methyl-2-pyridone respectively).

Original languageEnglish
Pages (from-to)1983-1985
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number19
DOIs
Publication statusPublished - 1 Dec 1995

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