New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

L F Jones, E K Brechin, D Collison, A Harrison, S J Teat, W Wernsdorfer

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)(10)(OMe)(6)(F)(10)(BTA)(20)(BTAH)(2)(MeOH)(13)(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

Original languageEnglish
Pages (from-to)2974-2975
Number of pages2
JournalChemical Communications
Issue number24
DOIs
Publication statusPublished - 2002

Keywords

  • SINGLE-MOLECULE MAGNETS
  • CLUSTERS
  • MODEL

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