New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

L F  Jones; E K  Brechin; D  Collison; A  Harrison; S J  Teat; W  Wernsdorfer

doi:10.1039/b209445b

New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

L F Jones, E K Brechin, D Collison, A Harrison, S J Teat, W Wernsdorfer

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)(10)(OMe)(6)(F)(10)(BTA)(20)(BTAH)(2)(MeOH)(13)(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

Original language	English
Pages (from-to)	2974-2975
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/b209445b
Publication status	Published - 2002

Keywords / Materials (for Non-textual outputs)

SINGLE-MOLECULE MAGNETS
CLUSTERS
MODEL

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10.1039/b209445b

Cite this

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title = "New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage",

abstract = "The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)(10)(OMe)(6)(F)(10)(BTA)(20)(BTAH)(2)(MeOH)(13)(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.",

keywords = "SINGLE-MOLECULE MAGNETS, CLUSTERS, MODEL",

author = "Jones, {L F} and Brechin, {E K} and D Collison and A Harrison and Teat, {S J} and W Wernsdorfer",

year = "2002",

doi = "10.1039/b209445b",

language = "English",

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journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

AU - Jones, L F

AU - Brechin, E K

AU - Collison, D

AU - Harrison, A

AU - Teat, S J

AU - Wernsdorfer, W

PY - 2002

Y1 - 2002

N2 - The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)(10)(OMe)(6)(F)(10)(BTA)(20)(BTAH)(2)(MeOH)(13)(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

AB - The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)(10)(OMe)(6)(F)(10)(BTA)(20)(BTAH)(2)(MeOH)(13)(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

KW - SINGLE-MOLECULE MAGNETS

KW - CLUSTERS

KW - MODEL

U2 - 10.1039/b209445b

DO - 10.1039/b209445b

M3 - Article

SN - 1359-7345

SP - 2974

EP - 2975

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

Abstract

Keywords / Materials (for Non-textual outputs)

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