New trimetallic sandwich complexes of platinum(0) and palladium(0)

Dominic C. Babbini; Kyle J. Cluff; Nathan B. Fisher; John C. Charbonneau; Gary S. Nichol; Stephanie K. Hurst

doi:10.1016/j.jorganchem.2012.03.033

New trimetallic sandwich complexes of platinum(0) and palladium(0)

Dominic C. Babbini, Kyle J. Cluff, Nathan B. Fisher, John C. Charbonneau, Gary S. Nichol, Stephanie K. Hurst

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2]2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium–platinum sandwich complexes could also be formed [PdnPt3-nTr2X3][Y] (X = Cl, Br and I, Y = NBu4+ or PBu4+).

Original language	English
Pages (from-to)	217-221
Journal	Journal of organometallic chemistry
Volume	713
DOIs	https://doi.org/10.1016/j.jorganchem.2012.03.033
Publication status	Published - 15 Aug 2012

Keywords / Materials (for Non-textual outputs)

Organometallic
Palladium
Platinum
Tropylium

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10.1016/j.jorganchem.2012.03.033

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@article{dcdddb6623394a1abd762b9012871767,

title = "New trimetallic sandwich complexes of platinum(0) and palladium(0)",

abstract = "The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2]2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium–platinum sandwich complexes could also be formed [PdnPt3-nTr2X3][Y] (X = Cl, Br and I, Y = NBu4+ or PBu4+).",

keywords = "Organometallic, Palladium, Platinum, Tropylium",

author = "Babbini, {Dominic C.} and Cluff, {Kyle J.} and Fisher, {Nathan B.} and Charbonneau, {John C.} and Nichol, {Gary S.} and Hurst, {Stephanie K.}",

year = "2012",

month = aug,

day = "15",

doi = "10.1016/j.jorganchem.2012.03.033",

language = "English",

volume = "713",

pages = "217--221",

journal = "Journal of organometallic chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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TY - JOUR

T1 - New trimetallic sandwich complexes of platinum(0) and palladium(0)

AU - Babbini, Dominic C.

AU - Cluff, Kyle J.

AU - Fisher, Nathan B.

AU - Charbonneau, John C.

AU - Nichol, Gary S.

AU - Hurst, Stephanie K.

PY - 2012/8/15

Y1 - 2012/8/15

N2 - The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2]2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium–platinum sandwich complexes could also be formed [PdnPt3-nTr2X3][Y] (X = Cl, Br and I, Y = NBu4+ or PBu4+).

AB - The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2]2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium–platinum sandwich complexes could also be formed [PdnPt3-nTr2X3][Y] (X = Cl, Br and I, Y = NBu4+ or PBu4+).

KW - Organometallic

KW - Palladium

KW - Platinum

KW - Tropylium

U2 - 10.1016/j.jorganchem.2012.03.033

DO - 10.1016/j.jorganchem.2012.03.033

M3 - Article

SN - 0022-328X

VL - 713

SP - 217

EP - 221

JO - Journal of organometallic chemistry

JF - Journal of organometallic chemistry

ER -

New trimetallic sandwich complexes of platinum(0) and palladium(0)

Abstract

Keywords / Materials (for Non-textual outputs)

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