Non-cyclopentadienyl titanium(III) - Magnesium hydride formation by reduction of an amidotitanium(IV) complex

Q F Mokuolu, P A Duckmanton, A J Blake, C Wilson, J B Love

Research output: Contribution to journalArticlepeer-review

Abstract

The reduction of an arylamido-based titanium(IV) chloride by magnesium has resulted in the formation of a unique, non-cyclopentadienyl titanium(III)-magnesium hydride with the concomitant intramolecular metalation of the arylamido ligands.

Original languageEnglish
Pages (from-to)4387-4389
Number of pages3
JournalOrganometallics
Volume22
Issue number22
DOIs
Publication statusPublished - 27 Oct 2003

Keywords

  • PI-ARENE COMPLEXES
  • HETEROBIMETALLIC COMPLEXES
  • CRYSTAL-STRUCTURES
  • TITANOCENE
  • LIGANDS
  • TETRAHYDROFURAN
  • CHEMISTRY
  • CHROMIUM

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