Non-cyclopentadienyl titanium(III) - Magnesium hydride formation by reduction of an amidotitanium(IV) complex

Q F  Mokuolu; P A  Duckmanton; A J  Blake; C  Wilson; J B  Love

doi:10.1021/om034164a

Non-cyclopentadienyl titanium(III) - Magnesium hydride formation by reduction of an amidotitanium(IV) complex

Q F Mokuolu, P A Duckmanton, A J Blake, C Wilson, J B Love

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

The reduction of an arylamido-based titanium(IV) chloride by magnesium has resulted in the formation of a unique, non-cyclopentadienyl titanium(III)-magnesium hydride with the concomitant intramolecular metalation of the arylamido ligands.

Original language	English
Pages (from-to)	4387-4389
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	22
DOIs	https://doi.org/10.1021/om034164a
Publication status	Published - 27 Oct 2003

Keywords / Materials (for Non-textual outputs)

PI-ARENE COMPLEXES
HETEROBIMETALLIC COMPLEXES
CRYSTAL-STRUCTURES
TITANOCENE
LIGANDS
TETRAHYDROFURAN
CHEMISTRY
CHROMIUM

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10.1021/om034164a

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title = "Non-cyclopentadienyl titanium(III) - Magnesium hydride formation by reduction of an amidotitanium(IV) complex",

abstract = "The reduction of an arylamido-based titanium(IV) chloride by magnesium has resulted in the formation of a unique, non-cyclopentadienyl titanium(III)-magnesium hydride with the concomitant intramolecular metalation of the arylamido ligands.",

keywords = "PI-ARENE COMPLEXES, HETEROBIMETALLIC COMPLEXES, CRYSTAL-STRUCTURES, TITANOCENE, LIGANDS, TETRAHYDROFURAN, CHEMISTRY, CHROMIUM",

author = "Mokuolu, {Q F} and Duckmanton, {P A} and Blake, {A J} and C Wilson and Love, {J B}",

year = "2003",

month = oct,

day = "27",

doi = "10.1021/om034164a",

language = "English",

volume = "22",

pages = "4387--4389",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "22",

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T1 - Non-cyclopentadienyl titanium(III) - Magnesium hydride formation by reduction of an amidotitanium(IV) complex

AU - Mokuolu, Q F

AU - Duckmanton, P A

AU - Blake, A J

AU - Wilson, C

AU - Love, J B

PY - 2003/10/27

Y1 - 2003/10/27

N2 - The reduction of an arylamido-based titanium(IV) chloride by magnesium has resulted in the formation of a unique, non-cyclopentadienyl titanium(III)-magnesium hydride with the concomitant intramolecular metalation of the arylamido ligands.

AB - The reduction of an arylamido-based titanium(IV) chloride by magnesium has resulted in the formation of a unique, non-cyclopentadienyl titanium(III)-magnesium hydride with the concomitant intramolecular metalation of the arylamido ligands.

KW - PI-ARENE COMPLEXES

KW - HETEROBIMETALLIC COMPLEXES

KW - CRYSTAL-STRUCTURES

KW - TITANOCENE

KW - LIGANDS

KW - TETRAHYDROFURAN

KW - CHEMISTRY

KW - CHROMIUM

U2 - 10.1021/om034164a

DO - 10.1021/om034164a

M3 - Article

SN - 0276-7333

VL - 22

SP - 4387

EP - 4389

JO - Organometallics

JF - Organometallics

IS - 22

ER -

Non-cyclopentadienyl titanium(III) - Magnesium hydride formation by reduction of an amidotitanium(IV) complex

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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