Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity

Mariolino Carta; Kadhurn J. Msayib; Peter M. Budd; Neil B. McKeown

doi:10.1021/ol800573m

Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity

Mariolino Carta, Kadhurn J. Msayib, Peter M. Budd, Neil B. McKeown^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.

Original language	English
Pages (from-to)	2641-2643
Number of pages	3
Journal	Organic letters
Volume	10
Issue number	13
DOIs	https://doi.org/10.1021/ol800573m
Publication status	Published - 3 Jul 2008

Keywords

HYDROGEN STORAGE MATERIALS
ABSOLUTE CONFIGURATION
1,1'-SPIROBIINDENE
PIMS
SPIROCONJUGATION
CONDENSATION
CATALYSIS
CATECHOL
ACETONE
SQUARES

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title = "Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity",

abstract = "The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.",

keywords = "HYDROGEN STORAGE MATERIALS, ABSOLUTE CONFIGURATION, 1,1'-SPIROBIINDENE, PIMS, SPIROCONJUGATION, CONDENSATION, CATALYSIS, CATECHOL, ACETONE, SQUARES",

author = "Mariolino Carta and Msayib, {Kadhurn J.} and Budd, {Peter M.} and McKeown, {Neil B.}",

year = "2008",

month = jul,

day = "3",

doi = "10.1021/ol800573m",

language = "English",

volume = "10",

pages = "2641--2643",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "13",

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TY - JOUR

T1 - Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity

AU - Carta, Mariolino

AU - Msayib, Kadhurn J.

AU - Budd, Peter M.

AU - McKeown, Neil B.

PY - 2008/7/3

Y1 - 2008/7/3

N2 - The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.

AB - The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.

KW - HYDROGEN STORAGE MATERIALS

KW - ABSOLUTE CONFIGURATION

KW - 1,1'-SPIROBIINDENE

KW - PIMS

KW - SPIROCONJUGATION

KW - CONDENSATION

KW - CATALYSIS

KW - CATECHOL

KW - ACETONE

KW - SQUARES

U2 - 10.1021/ol800573m

DO - 10.1021/ol800573m

M3 - Article

VL - 10

SP - 2641

EP - 2643

JO - Organic letters

JF - Organic letters

SN - 1523-7060

IS - 13

ER -

Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity

Abstract

Keywords

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