Novel zirconium complexes derived from C-2-symmetric diamide ligands; The X-ray crystal structure of [Zr(eta(1)-CH(2)Ph)(eta(2)-CH(2)Ph){(C6H3)(2)-2,2'-(NCH(2)C(6)H(4)Ph-4)(2)-6,6'-Me(2)}]

F G N Cloke, T J Geldbach, P B Hitchcock, J B Love

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

The novel alkene polymerisation cocatalysts [Zr(CH(2)Ph)(2)(ArDABP)] containing the biphenyl-bridged ligands 2,2'-di-(N-benzyl)amino-6,6'-dimethylbiphenyl (ArDABP, Ar = CH(2)C(6)H(4)(t)Bu-4 or CH2C6H4-Ph) display averaged C-2-symmetry in solution and an eta(2)-benzyl coordination mode in the solid state.

Original languageEnglish
Pages (from-to)343-345
Number of pages3
JournalJournal of organometallic chemistry
Volume506
Issue number1-2
Publication statusPublished - 11 Jan 1996

Keywords / Materials (for Non-textual outputs)

  • zirconium
  • diamide ligands
  • olefin polymerization
  • catalyses
  • crystal structure
  • M = ZR
  • MOLECULAR-STRUCTURE
  • BENZYL COMPLEXES
  • POLYMERIZATION
  • REACTIVITY
  • CHEMISTRY
  • TITANIUM
  • HAFNIUM
  • HF

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