Numerical investigation of NO emissions from an entrained flow reactor under oxy-coal conditions

L. Álvarez, M. Gharebaghi, J. M. Jones, M. Pourkashanian, A. Williams*, J. Riaza, C. Pevida, J. J. Pis, F. Rubiera

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The NO emissions of two anthracitic and three high volatile bituminous coals were experimentally and numerically studied under both air and oxy-fuel combustion conditions in an entrained flow reactor (EFR). Thermal decomposition experiments under N2 and CO2 atmospheres were carried out to determine the distribution of fuel-bound nitrogen between the volatile and char and the results compared with those obtained by means of the network pyrolysis model, FG-DVC (Functional Group-Depolymerisation Vaporisation Cross-linking). This code was also used as a pre-processing stage to predict the evolution of HCN and NH3 during devolatilisation of the coals. A Computational Fluid Dynamic (CFD) model was used to predict NO emissions under different O2/CO2 (21-35% O2) conditions in the EFR. Three different models were used. The first assumed that all of the fuel-bound nitrogen had been converted to HCN. The second assumed that all of the volatile nitrogen would evolve as HCN, and the char-N formed NO by an amount determined by a conversion factor. The third approach was similar to the second but it included NH3 as a precursor of NO as well. The NO emissions predicted with the third approach were in good agreement with the experimental results. A decrease in NO emissions was observed when N2 was replaced by CO2 for the same oxygen concentration for both the experimental and computed results. Higher NO emissions under O2/CO2 conditions were observed when the oxygen concentration was 30 or 35%.

Original languageEnglish
Pages (from-to)53-64
Number of pages12
JournalFuel Processing Technology
Volume93
Issue number1
DOIs
Publication statusPublished - 1 Jan 2012

Keywords

  • Computational Fluid Dynamics
  • NO emissions
  • Oxy-fuel combustion

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