Observation of a new high-energy, shallow-bound Rydberg state in I-2 by optical triple resonance

AM Sjodin; T Ridley; KP Lawley; RJ Donovan

doi:10.1016/j.cplett.2005.06.095

Observation of a new high-energy, shallow-bound Rydberg state in I-2 by optical triple resonance

AM Sjodin, T Ridley^*, KP Lawley, RJ Donovan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A new 0(u)(+)6s Rydberg state built on an excited ionic core of I-2 has been observed by optical triple resonance via the B(O-u(+)) valence and EOg+ (P-3(2)) ion-pair states with ionization detection. A vibrational progression, v = 0-27, was observed for selected rotational levels and molecular constants are presented. The Rydberg state is weakly bound and was determined to have an internuclear separation of 4.500 +/- 0.003 angstrom. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	110-115
Number of pages	6
Journal	Chemical Physics Letters
Volume	412
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2005.06.095
Publication status	Published - 25 Aug 2005

Keywords / Materials (for Non-textual outputs)

ION-PAIR STATES
PHOTOELECTRON-SPECTRA
ABSORPTION-SPECTRUM
FIELD-IONIZATION
IODINE MOLECULE
SPECTROSCOPY
EXCITATION
SYSTEM
I2

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10.1016/j.cplett.2005.06.095

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title = "Observation of a new high-energy, shallow-bound Rydberg state in I-2 by optical triple resonance",

abstract = "A new 0(u)(+)6s Rydberg state built on an excited ionic core of I-2 has been observed by optical triple resonance via the B(O-u(+)) valence and EOg+ (P-3(2)) ion-pair states with ionization detection. A vibrational progression, v = 0-27, was observed for selected rotational levels and molecular constants are presented. The Rydberg state is weakly bound and was determined to have an internuclear separation of 4.500 +/- 0.003 angstrom. (c) 2005 Elsevier B.V. All rights reserved.",

keywords = "ION-PAIR STATES, PHOTOELECTRON-SPECTRA, ABSORPTION-SPECTRUM, FIELD-IONIZATION, IODINE MOLECULE, SPECTROSCOPY, EXCITATION, SYSTEM, I2",

author = "AM Sjodin and T Ridley and KP Lawley and RJ Donovan",

year = "2005",

month = aug,

day = "25",

doi = "10.1016/j.cplett.2005.06.095",

language = "English",

volume = "412",

pages = "110--115",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "1-3",

}

TY - JOUR

T1 - Observation of a new high-energy, shallow-bound Rydberg state in I-2 by optical triple resonance

AU - Sjodin, AM

AU - Ridley, T

AU - Lawley, KP

AU - Donovan, RJ

PY - 2005/8/25

Y1 - 2005/8/25

N2 - A new 0(u)(+)6s Rydberg state built on an excited ionic core of I-2 has been observed by optical triple resonance via the B(O-u(+)) valence and EOg+ (P-3(2)) ion-pair states with ionization detection. A vibrational progression, v = 0-27, was observed for selected rotational levels and molecular constants are presented. The Rydberg state is weakly bound and was determined to have an internuclear separation of 4.500 +/- 0.003 angstrom. (c) 2005 Elsevier B.V. All rights reserved.

AB - A new 0(u)(+)6s Rydberg state built on an excited ionic core of I-2 has been observed by optical triple resonance via the B(O-u(+)) valence and EOg+ (P-3(2)) ion-pair states with ionization detection. A vibrational progression, v = 0-27, was observed for selected rotational levels and molecular constants are presented. The Rydberg state is weakly bound and was determined to have an internuclear separation of 4.500 +/- 0.003 angstrom. (c) 2005 Elsevier B.V. All rights reserved.

KW - ION-PAIR STATES

KW - PHOTOELECTRON-SPECTRA

KW - ABSORPTION-SPECTRUM

KW - FIELD-IONIZATION

KW - IODINE MOLECULE

KW - SPECTROSCOPY

KW - EXCITATION

KW - SYSTEM

KW - I2

U2 - 10.1016/j.cplett.2005.06.095

DO - 10.1016/j.cplett.2005.06.095

M3 - Article

SN - 0009-2614

VL - 412

SP - 110

EP - 115

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Observation of a new high-energy, shallow-bound Rydberg state in I-2 by optical triple resonance

Abstract

Keywords / Materials (for Non-textual outputs)

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