Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(ii) clusters

Robyn E. Fairbairn, Ross McLellan, Ruaraidh D. McIntosh, Maria A. Palacios, Euan K. Brechin, Scott J. Dalgarno

Research output: Contribution to journalArticlepeer-review

Abstract

Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear Cu(II) clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear Cu(II) cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.
Original languageEnglish
Pages (from-to)5292-5298
Number of pages7
JournalDalton Transactions
Volume43
Issue number14
Early online date12 Dec 2013
DOIs
Publication statusPublished - 2014

Keywords

  • CRYSTAL-STRUCTURE
  • COMPLEXES
  • CALIXARENE
  • METAL
  • GUEST
  • OXACALIXARENES
  • MAGNETS
  • IONS
  • K+

Fingerprint Dive into the research topics of 'Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(ii) clusters'. Together they form a unique fingerprint.

Cite this