Palladium-catalyzed hydroacyloxylation of ynamides

Donna L. Smith, William R. F. Goundry, Hon Wai Lam

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide alpha-acyloxyenamides.

Original languageEnglish
Pages (from-to)1505-1507
Number of pages3
JournalChemical Communications
Volume48
Issue number10
DOIs
Publication statusPublished - 2012

Keywords / Materials (for Non-textual outputs)

  • CARBOXYLIC-ACIDS
  • ENOL ESTERS
  • RUTHENIUM COMPLEXES
  • METAL VINYLIDENES
  • ANTI-MARKOVNIKOV
  • TERMINAL ALKYNES
  • CHIRAL YNAMIDES
  • VINYL ESTERS
  • DIPHENYLDITHIOPHOSPHINIC ACID
  • STEREOSELECTIVE-SYNTHESIS

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