Palladium-catalyzed hydroacyloxylation of ynamides

Donna L. Smith; William R. F. Goundry; Hon Wai Lam

doi:10.1039/c1cc13595c

Palladium-catalyzed hydroacyloxylation of ynamides

Donna L. Smith, William R. F. Goundry, Hon Wai Lam

Research output: Contribution to journal › Article › peer-review

Abstract

In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide alpha-acyloxyenamides.

Original language	English
Pages (from-to)	1505-1507
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc13595c
Publication status	Published - 2012

Keywords / Materials (for Non-textual outputs)

CARBOXYLIC-ACIDS
ENOL ESTERS
RUTHENIUM COMPLEXES
METAL VINYLIDENES
ANTI-MARKOVNIKOV
TERMINAL ALKYNES
CHIRAL YNAMIDES
VINYL ESTERS
DIPHENYLDITHIOPHOSPHINIC ACID
STEREOSELECTIVE-SYNTHESIS

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10.1039/c1cc13595c

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title = "Palladium-catalyzed hydroacyloxylation of ynamides",

abstract = "In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide alpha-acyloxyenamides.",

keywords = "CARBOXYLIC-ACIDS, ENOL ESTERS, RUTHENIUM COMPLEXES, METAL VINYLIDENES, ANTI-MARKOVNIKOV, TERMINAL ALKYNES, CHIRAL YNAMIDES, VINYL ESTERS, DIPHENYLDITHIOPHOSPHINIC ACID, STEREOSELECTIVE-SYNTHESIS",

author = "Smith, \{Donna L.\} and Goundry, \{William R. F.\} and Lam, \{Hon Wai\}",

year = "2012",

doi = "10.1039/c1cc13595c",

language = "English",

volume = "48",

pages = "1505--1507",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - Palladium-catalyzed hydroacyloxylation of ynamides

AU - Smith, Donna L.

AU - Goundry, William R. F.

AU - Lam, Hon Wai

PY - 2012

Y1 - 2012

N2 - In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide alpha-acyloxyenamides.

AB - In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide alpha-acyloxyenamides.

KW - CARBOXYLIC-ACIDS

KW - ENOL ESTERS

KW - RUTHENIUM COMPLEXES

KW - METAL VINYLIDENES

KW - ANTI-MARKOVNIKOV

KW - TERMINAL ALKYNES

KW - CHIRAL YNAMIDES

KW - VINYL ESTERS

KW - DIPHENYLDITHIOPHOSPHINIC ACID

KW - STEREOSELECTIVE-SYNTHESIS

UR - https://www.scopus.com/pages/publications/84862908648

U2 - 10.1039/c1cc13595c

DO - 10.1039/c1cc13595c

M3 - Article

SN - 1359-7345

VL - 48

SP - 1505

EP - 1507

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Palladium-catalyzed hydroacyloxylation of ynamides

Abstract

Keywords / Materials (for Non-textual outputs)

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