Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer

Christopher Bejger; Christina M. Davis; Jung Su Park; Vincent M. Lynch; Jason B. Love; Jonathan L. Sessler

doi:10.1021/ol201992x

Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer

Christopher Bejger, Christina M. Davis, Jung Su Park, Vincent M. Lynch, Jason B. Love, Jonathan L. Sessler

Research output: Contribution to journal › Article › peer-review

Abstract

Ditopic metalation of a flexible "Pacman"-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.

Original language	English
Pages (from-to)	4902-4905
Number of pages	4
Journal	Organic letters
Volume	13
Issue number	18
DOIs	https://doi.org/10.1021/ol201992x
Publication status	Published - 16 Sept 2011

Keywords / Materials (for Non-textual outputs)

BASE EXPANDED PORPHYRIN
SCHIFF-BASE
ROOM-TEMPERATURE
COMPLEXES
ENCAPSULATION
REDUCTION
LIGANDS
STATES
ANION

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10.1021/ol201992x

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title = "Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer",

abstract = "Ditopic metalation of a flexible {"}Pacman{"}-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.",

keywords = "BASE EXPANDED PORPHYRIN, SCHIFF-BASE, ROOM-TEMPERATURE, COMPLEXES, ENCAPSULATION, REDUCTION, LIGANDS, STATES, ANION",

author = "Christopher Bejger and Davis, {Christina M.} and Park, {Jung Su} and Lynch, {Vincent M.} and Love, {Jason B.} and Sessler, {Jonathan L.}",

year = "2011",

month = sep,

day = "16",

doi = "10.1021/ol201992x",

language = "English",

volume = "13",

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journal = "Organic letters",

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T1 - Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer

AU - Bejger, Christopher

AU - Davis, Christina M.

AU - Park, Jung Su

AU - Lynch, Vincent M.

AU - Love, Jason B.

AU - Sessler, Jonathan L.

PY - 2011/9/16

Y1 - 2011/9/16

N2 - Ditopic metalation of a flexible "Pacman"-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.

AB - Ditopic metalation of a flexible "Pacman"-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.

KW - BASE EXPANDED PORPHYRIN

KW - SCHIFF-BASE

KW - ROOM-TEMPERATURE

KW - COMPLEXES

KW - ENCAPSULATION

KW - REDUCTION

KW - LIGANDS

KW - STATES

KW - ANION

UR - http://www.scopus.com/inward/record.url?scp=80052714256&partnerID=8YFLogxK

U2 - 10.1021/ol201992x

DO - 10.1021/ol201992x

M3 - Article

SN - 1523-7060

VL - 13

SP - 4902

EP - 4905

JO - Organic letters

JF - Organic letters

IS - 18

ER -

Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer

Abstract

Keywords / Materials (for Non-textual outputs)

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