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The structure of the phosphinyl radical, (P) over dot R-2 [R = CH(SiMe3)(2)], has been determined by gas-phase electron diffraction (GED) together with ab initio molecular orbital calculations, and that of the corresponding diphosphine, (PR2)(2), has been established by X-ray crystallography; the diphosphine behaves as an energy storage reservoir.
|Publication status||Published - 2000|
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- 1 Finished
1/10/00 → 31/03/07